CO2-Induced Spin-State Switching at Room Temperature in a Monomeric Cobalt(II) Complex with the Porous Nature
Dr. Manabu Nakaya
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorDr. Wataru Kosaka
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, 980-8577 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Hitoshi Miyasaka
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, 980-8577 Japan
Search for more papers by this authorYuki Komatsumaru
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorDr. Shogo Kawaguchi
Diffraction & Scattering Division Japan, Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 ( Japan
Search for more papers by this authorDr. Kunihisa Sugimoto
Diffraction & Scattering Division Japan, Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 ( Japan
Search for more papers by this authorDr. Yingjie Zhang
Australian Nuclear Science and Technology Organization, Locked Bag 2001, Kirrawee DC, NSW, 2232 Australia
Search for more papers by this authorDr. Masaaki Nakamura
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorLeonard F. Lindoy
School of Chemistry, The University of Sydney, Sydney, NSW, 2006 Australia
Search for more papers by this authorCorresponding Author
Prof. Dr. Shinya Hayami
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Institute of Pulsed Power Science (IPPS), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorDr. Manabu Nakaya
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorDr. Wataru Kosaka
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, 980-8577 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Hitoshi Miyasaka
Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, 980-8577 Japan
Search for more papers by this authorYuki Komatsumaru
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorDr. Shogo Kawaguchi
Diffraction & Scattering Division Japan, Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 ( Japan
Search for more papers by this authorDr. Kunihisa Sugimoto
Diffraction & Scattering Division Japan, Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 ( Japan
Search for more papers by this authorDr. Yingjie Zhang
Australian Nuclear Science and Technology Organization, Locked Bag 2001, Kirrawee DC, NSW, 2232 Australia
Search for more papers by this authorDr. Masaaki Nakamura
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorLeonard F. Lindoy
School of Chemistry, The University of Sydney, Sydney, NSW, 2006 Australia
Search for more papers by this authorCorresponding Author
Prof. Dr. Shinya Hayami
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Institute of Pulsed Power Science (IPPS), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto, 860-8555 Japan
Search for more papers by this authorAbstract
CO2-responsive spin-state conversion between high-spin (HS) and low-spin (LS) states at room temperature was achieved in a monomeric cobalt(II) complex. A neutral cobalt(II) complex, [CoII(COO-terpy)2]⋅4 H2O (1⋅4 H2O), stably formed cavities generated via π–π stacking motifs and hydrogen bond networks, resulting in the accommodation of four water molecules. Crystalline 1⋅4 H2O transformed to solvent-free 1 without loss of porosity by heating to 420 K. Compound 1 exhibited a selective CO2 adsorption via a gate-open type of the structural modification. Furthermore, the HS/LS transition temperature (T1/2) was able to be tuned by the CO2 pressure over a wide temperature range. Unlike 1 exhibits the HS state at 290 K, the CO2-accomodated form 1⊃CO2 (P
=110 kPa) was stabilized in the LS state at 290 K, probably caused by a chemical pressure effect by CO2 accommodation, which provides reversible spin-state conversion by introducing/evacuating CO2 gas into/from 1.
Conflict of interest
The authors declare no conflict of interest.
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