Copper-Catalyzed Regioselective Borocarbonylative Coupling of Unactivated Alkenes with Alkyl Halides: Synthesis of β-Boryl Ketones
Fu-Peng Wu
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorYang Yuan
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorClaas Schünemann
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorProf. Dr. Paul C. J. Kamer
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Xiao-Feng Wu
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, 310018 P. R. China
Search for more papers by this authorFu-Peng Wu
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorYang Yuan
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorClaas Schünemann
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorProf. Dr. Paul C. J. Kamer
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Xiao-Feng Wu
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, 310018 P. R. China
Search for more papers by this authorAbstract
The borocarbonylative coupling of unactivated alkenes with alkyl halides remains a challenge. In this communication, a Cu-catalyzed borocarbonylative coupling of unactivated alkenes with alkyl halides for the synthesis of β-boryl ketones has been developed. A broad range of β-boryl ketone derivatives was prepared in moderate to excellent yields with complete regioselectivity.
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