A Long Cycle-Life High-Voltage Spinel Lithium-Ion Battery Electrode Achieved by Site-Selective Doping
Gemeng Liang
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorZhibin Wu
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorDr. Christophe Didier
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organization, Sydney, NSW, Australia
Search for more papers by this authorDr. Wenchao Zhang
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorDr. Jing Cuan
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorProf. Baohua Li
Graduate School at Shenzhen, Tsinghua University, Shenzhen, 518055 P. R. China
Search for more papers by this authorKuan-Yu Ko
Industrial Technology Research Institute, Hsinchu, Taiwan) (China
Search for more papers by this authorPo-Yang Hung
Industrial Technology Research Institute, Hsinchu, Taiwan) (China
Search for more papers by this authorDr. Cheng-Zhang Lu
Industrial Technology Research Institute, Hsinchu, Taiwan) (China
Search for more papers by this authorDr. Yuanzhen Chen
School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049 P. R. China
Search for more papers by this authorDr. Grzegorz Leniec
Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, Al. Piastów, 17, 70-310 Szczecin, Poland
Search for more papers by this authorDr. Sławomir Maksymilian Kaczmarek
Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, Al. Piastów, 17, 70-310 Szczecin, Poland
Search for more papers by this authorDr. Bernt Johannessen
Australian Synchrotron, Australian Nuclear Science and Technology Organization, 800 Blackburn Road, Clayton, Victoria, 3168 Australia
Search for more papers by this authorDr. Lars Thomsen
Australian Synchrotron, Australian Nuclear Science and Technology Organization, 800 Blackburn Road, Clayton, Victoria, 3168 Australia
Search for more papers by this authorDr. Vanessa K. Peterson
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organization, Sydney, NSW, Australia
Search for more papers by this authorCorresponding Author
Dr. Wei Kong Pang
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorCorresponding Author
Prof. Zaiping Guo
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorGemeng Liang
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorZhibin Wu
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorDr. Christophe Didier
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organization, Sydney, NSW, Australia
Search for more papers by this authorDr. Wenchao Zhang
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorDr. Jing Cuan
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorProf. Baohua Li
Graduate School at Shenzhen, Tsinghua University, Shenzhen, 518055 P. R. China
Search for more papers by this authorKuan-Yu Ko
Industrial Technology Research Institute, Hsinchu, Taiwan) (China
Search for more papers by this authorPo-Yang Hung
Industrial Technology Research Institute, Hsinchu, Taiwan) (China
Search for more papers by this authorDr. Cheng-Zhang Lu
Industrial Technology Research Institute, Hsinchu, Taiwan) (China
Search for more papers by this authorDr. Yuanzhen Chen
School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049 P. R. China
Search for more papers by this authorDr. Grzegorz Leniec
Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, Al. Piastów, 17, 70-310 Szczecin, Poland
Search for more papers by this authorDr. Sławomir Maksymilian Kaczmarek
Faculty of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology in Szczecin, Al. Piastów, 17, 70-310 Szczecin, Poland
Search for more papers by this authorDr. Bernt Johannessen
Australian Synchrotron, Australian Nuclear Science and Technology Organization, 800 Blackburn Road, Clayton, Victoria, 3168 Australia
Search for more papers by this authorDr. Lars Thomsen
Australian Synchrotron, Australian Nuclear Science and Technology Organization, 800 Blackburn Road, Clayton, Victoria, 3168 Australia
Search for more papers by this authorDr. Vanessa K. Peterson
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organization, Sydney, NSW, Australia
Search for more papers by this authorCorresponding Author
Dr. Wei Kong Pang
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorCorresponding Author
Prof. Zaiping Guo
Faculty of Engineering, Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia
Search for more papers by this authorAbstract
Spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode candidate for the next-generation high energy-density lithium-ion batteries (LIBs). Unfortunately, the application of LNMO is hindered by its poor cycle stability. Now, site-selectively doped LNMO electrode is prepared with exceptional durability. In this work, Mg is selectively doped onto both tetrahedral (8a) and octahedral (16c) sites in the Fd
m structure. This site-selective doping not only suppresses unfavorable two-phase reactions and stabilizes the LNMO structure against structural deformation, but also mitigates the dissolution of Mn during cycling. Mg-doped LNMOs exhibit extraordinarily stable electrochemical performance in both half-cells and prototype full-batteries with novel TiNb2O7 counter-electrodes. This work pioneers an atomic-doping engineering strategy for electrode materials that could be extended to other energy materials to create high-performance devices.
Conflict of interest
The authors declare no conflict of interest.
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