Sodium- and Potassium-Hydrate Melts Containing Asymmetric Imide Anions for High-Voltage Aqueous Batteries
Dr. Qifeng Zheng
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
These authors contributed equally to this work.
Search for more papers by this authorShota Miura
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
These authors contributed equally to this work.
Search for more papers by this authorKasumi Miyazaki
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Search for more papers by this authorSeongjae Ko
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Search for more papers by this authorEriko Watanabe
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Search for more papers by this authorMasaki Okoshi
Department of Chemistry and Biochemistry, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Search for more papers by this authorChien-Pin Chou
Waseda Research Institute for Science and Engineering (WISE), Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Search for more papers by this authorYoshifumi Nishimura
Waseda Research Institute for Science and Engineering (WISE), Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Search for more papers by this authorProf. Hiromi Nakai
Department of Chemistry and Biochemistry, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Waseda Research Institute for Science and Engineering (WISE), Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Search for more papers by this authorTakeshi Kamiya
Mitsubishi Materials Electronic Chemicals Co., Ltd., 3-1-6, Barajima, Akita city, Akita, 010-8585 Japan
Search for more papers by this authorTsunetoshi Honda
Advanced Products Company, Mitsubishi Materials Corporation, 1-6-1, Yokoami, Sumida-ku, Tokyo, 130-0015 Japan
Search for more papers by this authorJun Akikusa
Central Research Institute, Mitsubishi Materials Corporation, 1002-14, Mukohyama, Naka-shi, Ibaraki, 311-0102 Japan
Search for more papers by this authorProf. Yuki Yamada
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Search for more papers by this authorCorresponding Author
Prof. Atsuo Yamada
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Search for more papers by this authorDr. Qifeng Zheng
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
These authors contributed equally to this work.
Search for more papers by this authorShota Miura
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
These authors contributed equally to this work.
Search for more papers by this authorKasumi Miyazaki
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Search for more papers by this authorSeongjae Ko
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Search for more papers by this authorEriko Watanabe
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Search for more papers by this authorMasaki Okoshi
Department of Chemistry and Biochemistry, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Search for more papers by this authorChien-Pin Chou
Waseda Research Institute for Science and Engineering (WISE), Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Search for more papers by this authorYoshifumi Nishimura
Waseda Research Institute for Science and Engineering (WISE), Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Search for more papers by this authorProf. Hiromi Nakai
Department of Chemistry and Biochemistry, Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Waseda Research Institute for Science and Engineering (WISE), Waseda University, 3-4-1, Okubo, Shinjuku-ku, Tokyo, 169-8555 Japan
Search for more papers by this authorTakeshi Kamiya
Mitsubishi Materials Electronic Chemicals Co., Ltd., 3-1-6, Barajima, Akita city, Akita, 010-8585 Japan
Search for more papers by this authorTsunetoshi Honda
Advanced Products Company, Mitsubishi Materials Corporation, 1-6-1, Yokoami, Sumida-ku, Tokyo, 130-0015 Japan
Search for more papers by this authorJun Akikusa
Central Research Institute, Mitsubishi Materials Corporation, 1002-14, Mukohyama, Naka-shi, Ibaraki, 311-0102 Japan
Search for more papers by this authorProf. Yuki Yamada
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Search for more papers by this authorCorresponding Author
Prof. Atsuo Yamada
Department of Chemical System Engineering, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, 113-8656 Tokyo, Japan
Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, 1-30, Goryo-Ohara, Nishikyo-ku, Kyoto, 615-8245 Japan
Search for more papers by this authorAbstract
Aqueous Na- or K-ion batteries could virtually eliminate the safety and cost concerns raised from Li-ion batteries, but their widespread applications have generally suffered from narrow electrochemical potential window (ca. 1.23 V) of aqueous electrolytes that leads to low energy density. Herein, by exploring optimized eutectic systems of Na and K salts with asymmetric imide anions, we discovered, for the first time, room-temperature hydrate melts for Na and K systems, which are the second and third alkali metal hydrate melts reported since the first discovery of Li hydrate melt by our group in 2016. The newly discovered Na- and K- hydrate melts could significantly extend the potential window up to 2.7 and 2.5 V (at Pt electrode), respectively, owing to the merit that almost all water molecules participate in the Na+ or K+ hydration shells. As a proof-of-concept, a prototype Na3V2(PO4)2F3|NaTi2(PO4)3 aqueous Na-ion full-cell with the Na-hydrate-melt electrolyte delivers an average discharge voltage of 1.75 V, that is among the highest value ever reported for all aqueous Na-ion batteries.
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