Metal–Organic Framework-Activated Carbon Composite Materials for the Removal of Ammonia from Contaminated Airstreams
Corresponding Author
Lauren N. McHugh
School of Chemistry, University of St Andrews, St Andrews, KY16 9ST UK
Search for more papers by this authorAngela Terracina
Dipartimento di Fisica e Chimica, Università delgi Studi di Palermo, Palermo, 3690123 Italy
Search for more papers by this authorDr. Paul S. Wheatley
School of Chemistry, University of St Andrews, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. Gianpiero Buscarino
Dipartimento di Fisica e Chimica, Università delgi Studi di Palermo, Palermo, 3690123 Italy
Search for more papers by this authorMartin W. Smith
CBR Division, Dstl Porton Down, Salisbury, SP4 0JQ UK
Search for more papers by this authorProf. Russell E. Morris
School of Chemistry, University of St Andrews, St Andrews, KY16 9ST UK
Search for more papers by this authorCorresponding Author
Lauren N. McHugh
School of Chemistry, University of St Andrews, St Andrews, KY16 9ST UK
Search for more papers by this authorAngela Terracina
Dipartimento di Fisica e Chimica, Università delgi Studi di Palermo, Palermo, 3690123 Italy
Search for more papers by this authorDr. Paul S. Wheatley
School of Chemistry, University of St Andrews, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. Gianpiero Buscarino
Dipartimento di Fisica e Chimica, Università delgi Studi di Palermo, Palermo, 3690123 Italy
Search for more papers by this authorMartin W. Smith
CBR Division, Dstl Porton Down, Salisbury, SP4 0JQ UK
Search for more papers by this authorProf. Russell E. Morris
School of Chemistry, University of St Andrews, St Andrews, KY16 9ST UK
Search for more papers by this authorAbstract
Metal–organic frameworks (MOFs) are a class of porous materials that show promise in the removal of toxic industrial chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.
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