Highly Selective Photoreduction of CO2 with Suppressing H2 Evolution over Monolayer Layered Double Hydroxide under Irradiation above 600 nm
Ling Tan
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Si-Min Xu
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorZelin Wang
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorYanqi Xu
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorXian Wang
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorXiaojie Hao
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorSha Bai
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorChenjun Ning
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorYu Wang
Department of Physics, Beijing Normal University, Beijing, 100875 P. R. China
Search for more papers by this authorProf. Wenkai Zhang
Department of Physics, Beijing Normal University, Beijing, 100875 P. R. China
Search for more papers by this authorYun Kyung Jo
Center for Hybrid Interfacial Chemical Structure (CICS), Department of Chemistry and Nanoscience, College of Natural Sciences, Ewha Womans University, Seoul, 03760 Republic of Korea
Search for more papers by this authorProf. Seong-Ju Hwang
Center for Hybrid Interfacial Chemical Structure (CICS), Department of Chemistry and Nanoscience, College of Natural Sciences, Ewha Womans University, Seoul, 03760 Republic of Korea
Search for more papers by this authorProf. Xingzhong Cao
Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorDr. Xusheng Zheng
School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorProf. Hong Yan
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yufei Zhao
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorCorresponding Author
Dr. Haohong Duan
Department of Chemistry, Tsinghua University, 30 Shuangqing Rd, Haidian Qu, Beijing Shi, 100084 China
Search for more papers by this authorCorresponding Author
Prof. Yu-Fei Song
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorLing Tan
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Si-Min Xu
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorZelin Wang
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorYanqi Xu
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorXian Wang
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorXiaojie Hao
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorSha Bai
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorChenjun Ning
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorYu Wang
Department of Physics, Beijing Normal University, Beijing, 100875 P. R. China
Search for more papers by this authorProf. Wenkai Zhang
Department of Physics, Beijing Normal University, Beijing, 100875 P. R. China
Search for more papers by this authorYun Kyung Jo
Center for Hybrid Interfacial Chemical Structure (CICS), Department of Chemistry and Nanoscience, College of Natural Sciences, Ewha Womans University, Seoul, 03760 Republic of Korea
Search for more papers by this authorProf. Seong-Ju Hwang
Center for Hybrid Interfacial Chemical Structure (CICS), Department of Chemistry and Nanoscience, College of Natural Sciences, Ewha Womans University, Seoul, 03760 Republic of Korea
Search for more papers by this authorProf. Xingzhong Cao
Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorDr. Xusheng Zheng
School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorProf. Hong Yan
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yufei Zhao
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorCorresponding Author
Dr. Haohong Duan
Department of Chemistry, Tsinghua University, 30 Shuangqing Rd, Haidian Qu, Beijing Shi, 100084 China
Search for more papers by this authorCorresponding Author
Prof. Yu-Fei Song
State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029 P. R. China
Search for more papers by this authorAbstract
Although progress has been made to improve photocatalytic CO2 reduction under visible light (λ>400 nm), the development of photocatalysts that can work under a longer wavelength (λ>600 nm) remains a challenge. Now, a heterogeneous photocatalyst system consisting of a ruthenium complex and a monolayer nickel-alumina layered double hydroxide (NiAl-LDH), which act as light-harvesting and catalytic units for selective photoreduction of CO2 and H2O into CH4 and CO under irradiation with λ>400 nm. By precisely tuning the irradiation wavelength, the selectivity of CH4 can be improved to 70.3 %, and the H2 evolution reaction can be completely suppressed under irradiation with λ>600 nm. The photogenerated electrons matching the energy levels of photosensitizer and m-NiAl-LDH only localized at the defect state, providing a driving force of 0.313 eV to overcome the Gibbs free energy barrier of CO2 reduction to CH4 (0.127 eV), rather than that for H2 evolution (0.425 eV).
Conflict of interest
The authors declare no conflict of interest.
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