A High-Voltage Molecular-Engineered Organic Sensitizer–Iron Redox Shuttle Pair: 1.4 V DSSC and 3.3 V SSM-DSSC Devices
Roberta R. Rodrigues
Department of Chemistry and Biochemistry, University of Mississippi, 481 Coulter Hall, University, MS, 38677 USA
Search for more papers by this authorDr. Hammad Cheema
Department of Chemistry and Biochemistry, University of Mississippi, 481 Coulter Hall, University, MS, 38677 USA
Search for more papers by this authorCorresponding Author
Prof. Jared H. Delcamp
Department of Chemistry and Biochemistry, University of Mississippi, 481 Coulter Hall, University, MS, 38677 USA
Search for more papers by this authorRoberta R. Rodrigues
Department of Chemistry and Biochemistry, University of Mississippi, 481 Coulter Hall, University, MS, 38677 USA
Search for more papers by this authorDr. Hammad Cheema
Department of Chemistry and Biochemistry, University of Mississippi, 481 Coulter Hall, University, MS, 38677 USA
Search for more papers by this authorCorresponding Author
Prof. Jared H. Delcamp
Department of Chemistry and Biochemistry, University of Mississippi, 481 Coulter Hall, University, MS, 38677 USA
Search for more papers by this authorAbstract
The development of high voltage solar cells is an attractive way to use sunlight for solar-to-fuel devices, multijunction solar-to-electric systems, and to power limited-area consumer electronics. By designing a low-oxidation-potential organic dye (RR9)/redox shuttle (Fe(bpy)33+/2+) pair for dye-sensitized solar-cell (DSSC) devices, the highest single device photovoltage (1.42 V) has been realized for a DSSC not relying on doped TiO2. Additionally, Fe(bpy)33+/2+ offers a robust, readily tunable ligand platform for redox potential tuning. RR9 can be regenerated with a low driving force (190 mV), and by utilizing the RR9/Fe(bpy)33+/2+ redox shuttle pair in a subcell for a sequential series multijunction (SSM)-DSSC system, one of the highest known three subcell photovoltage was attained for any solar-cell technology (3.34 V, >1.0 V per subcell).
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