Eight-Electron Silver and Mixed Gold/Silver Nanoclusters Stabilized by Selenium Donor Ligands
Wan-Ting Chang
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorPo-Yi Lee
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorJian-Hong Liao
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorDr. Kiran Kumarvarma Chakrahari
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorDr. Samia Kahlal
UMR-CNRS, 6226 “, Institut des Sciences Chimiques de Rennes”, University de Rennes 1, 35042 Rennes Cedex, France
Search for more papers by this authorDr. Yu-Chiao Liu
Institute of Chemistry, Academica Sinica, Taipei, 115 Taiwan R.O.C.
Search for more papers by this authorDr. Ming-Hsi Chiang
Institute of Chemistry, Academica Sinica, Taipei, 115 Taiwan R.O.C.
Search for more papers by this authorCorresponding Author
Prof. Jean-Yves Saillard
UMR-CNRS, 6226 “, Institut des Sciences Chimiques de Rennes”, University de Rennes 1, 35042 Rennes Cedex, France
Search for more papers by this authorCorresponding Author
Prof. C. W. Liu
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorWan-Ting Chang
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorPo-Yi Lee
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorJian-Hong Liao
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorDr. Kiran Kumarvarma Chakrahari
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorDr. Samia Kahlal
UMR-CNRS, 6226 “, Institut des Sciences Chimiques de Rennes”, University de Rennes 1, 35042 Rennes Cedex, France
Search for more papers by this authorDr. Yu-Chiao Liu
Institute of Chemistry, Academica Sinica, Taipei, 115 Taiwan R.O.C.
Search for more papers by this authorDr. Ming-Hsi Chiang
Institute of Chemistry, Academica Sinica, Taipei, 115 Taiwan R.O.C.
Search for more papers by this authorCorresponding Author
Prof. Jean-Yves Saillard
UMR-CNRS, 6226 “, Institut des Sciences Chimiques de Rennes”, University de Rennes 1, 35042 Rennes Cedex, France
Search for more papers by this authorCorresponding Author
Prof. C. W. Liu
Department of Chemistry, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd. Shoufeng, Hualien, 97401 Taiwan R.O.C.
Search for more papers by this authorAbstract
The first atomically and structurally precise silver-nanoclusters stabilized by Se-donor ligands, [Ag20{Se2P(OiPr)2}12] (3) and [Ag21{Se2P(OEt)2}12]+(4), were isolated by ligand replacement reaction of [Ag20{S2P(OiPr)2}12] (1) and [Ag21{S2P(OiPr)2}12]+ (2), respectively. Furthermore, doping reactions of 4 with Au(PPh3)Cl resulted in the formation of [AuAg20{Se2P(OEt)2}12]+ (5). Structures of 3, 4, and 5 were determined by single-crystal X-ray diffraction. The anatomy of cluster 3 with an Ag20 core having C3 symmetry is very similar to that of its dithiophosphate analogue 1. Clusters 4 and 5 exhibit an Ag21 and Au@Ag20 core of Oh symmetry composed of eight silver capping atoms in a cubic arrangement and encapsulating an Ag13 and Au@Ag12 centered icosahedron, respectively. Both ligand exchange and heteroatom doping result in significant changes in optical and emissive properties for chalcogen-passivated silver nanoparticles, which have been theoretically confirmed as 8-electron superatoms.
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