Divalent Thulium Triflate: A Structural and Spectroscopic Study
Mathieu Xémard
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorArnaud Jaoul
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorMarie Cordier
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorFlorian Molton
Département de Chimie Moléculaire, Grenoble Université, CNRS, Avenue de la Chimie, Saint Martin d'Hères, France
Search for more papers by this authorDr. Olivier Cador
Institut des Sciences Chimique de Rennes, UMR 6226 CNRS, Université de Rennes 1, 263 avenue du Général Leclerc, 35042 Rennes cedex, France
Search for more papers by this authorDr. Boris Le Guennic
Institut des Sciences Chimique de Rennes, UMR 6226 CNRS, Université de Rennes 1, 263 avenue du Général Leclerc, 35042 Rennes cedex, France
Search for more papers by this authorDr. Carole Duboc
Département de Chimie Moléculaire, Grenoble Université, CNRS, Avenue de la Chimie, Saint Martin d'Hères, France
Search for more papers by this authorDr. Olivier Maury
Univ Lyon, ENS Lyon, CNRS, Université Claude Bernard Lyon 1, UMR 5182, Laboratoire de Chimie, 69342 Lyon, France
Search for more papers by this authorDr. Carine Clavaguéra
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Laboratoire de Chimie Physique, CNRS, Université Paris Sud, Université Paris-Saclay, 15 avenue Jean Perrin, 91405 Orsay cedex, France
Search for more papers by this authorCorresponding Author
Dr. Grégory Nocton
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorMathieu Xémard
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorArnaud Jaoul
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorMarie Cordier
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorFlorian Molton
Département de Chimie Moléculaire, Grenoble Université, CNRS, Avenue de la Chimie, Saint Martin d'Hères, France
Search for more papers by this authorDr. Olivier Cador
Institut des Sciences Chimique de Rennes, UMR 6226 CNRS, Université de Rennes 1, 263 avenue du Général Leclerc, 35042 Rennes cedex, France
Search for more papers by this authorDr. Boris Le Guennic
Institut des Sciences Chimique de Rennes, UMR 6226 CNRS, Université de Rennes 1, 263 avenue du Général Leclerc, 35042 Rennes cedex, France
Search for more papers by this authorDr. Carole Duboc
Département de Chimie Moléculaire, Grenoble Université, CNRS, Avenue de la Chimie, Saint Martin d'Hères, France
Search for more papers by this authorDr. Olivier Maury
Univ Lyon, ENS Lyon, CNRS, Université Claude Bernard Lyon 1, UMR 5182, Laboratoire de Chimie, 69342 Lyon, France
Search for more papers by this authorDr. Carine Clavaguéra
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Laboratoire de Chimie Physique, CNRS, Université Paris Sud, Université Paris-Saclay, 15 avenue Jean Perrin, 91405 Orsay cedex, France
Search for more papers by this authorCorresponding Author
Dr. Grégory Nocton
LCM, Ecole polytechnique, CNRS, Université Paris-Saclay, Route de Saclay, 91128 Palaiseau cedex, France
Search for more papers by this authorAbstract
The first molecular TmII luminescence measurements are reported along with rare magnetic, X and Q bands EPR studies. Access to simple and soluble molecular divalent lanthanide complexes is highly sought for small-molecule activation studies and organic transformations using single-electron transfer processes. However, owing to their low stability and propensity to disproportionate, these complexes are hard to synthetize and their electronic properties are therefore almost unexplored. Herein we present the synthesis of [Tm(μ-OTf)2(dme)2]n, a rare and simple coordination compound of divalent thulium that can be seen as a promising starting material for the synthesis of more elaborated complexes. This reactive complex was structurally characterized by X-ray diffraction analysis and its electronic structure has been compared with that of its halide cousin TmI2(dme)3.
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References
- 1P. Girard, J. L. Namy, H. B. Kagan, J. Am. Chem. Soc. 1980, 102, 2693–2698.
- 2J. K. Howell, L. L. Pytlewski, J. Less-Common Met. 1969, 18, 437–439.
- 3
- 3aT. D. Tilley, R. A. Andersen, B. Spencer, H. Ruben, A. Zalkin, D. H. Templeton, Inorg. Chem. 1980, 19, 2999–3003;
- 3bW. J. Evans, I. Bloom, W. E. Hunter, J. L. Atwood, J. Am. Chem. Soc. 1981, 103, 6507–6508.
- 4
- 4aG. Nocton, W. L. Lukens, C. H. Booth, S. S. Rozenel, S. A. Melding, L. Maron, R. A. Andersen, J. Am. Chem. Soc. 2014, 136, 8626–8641;
- 4bG. Nocton, C. H. Booth, L. Maron, R. A. Andersen, Organometallics 2013, 32, 1150–1158;
- 4cG. Nocton, L. Ricard, Chem. Commun. 2015, 51, 3578–3581;
- 4dL. Jacquot, M. Xémard, C. Clavaguéra, G. Nocton, Organometallics 2014, 33, 4100–4106.
- 5H. B. Kagan, Tetrahedron 2003, 59, 10351–10372.
- 6M. Szostak, D. J. Procter, Angew. Chem. Int. Ed. 2012, 51, 9238–9256; Angew. Chem. 2012, 124, 9372–9390.
- 7
- 7aM. N. Bochkarev, A. A. Fagin, Chem. Eur. J. 1999, 5, 2990–2992;
10.1002/(SICI)1521-3765(19991001)5:10<2990::AID-CHEM2990>3.0.CO;2-U CAS Web of Science® Google Scholar
- 7bM. N. Bochkarev, A. A. Fagin, Russ. Chem. Bull. 1999, 48, 1187–1188;
- 7cM. N. Bochkarev, I. L. Fedushkin, S. Dechert, A. A. Fagin, H. Schumann, Angew. Chem. Int. Ed. 2001, 40, 3176–3178;
10.1002/1521-3773(20010903)40:17<3176::AID-ANIE3176>3.0.CO;2-Y CAS PubMed Web of Science® Google ScholarAngew. Chem. 2001, 113, 3268–3270;
- 7dM. N. Bochkarev, I. L. Fedushkin, A. A. Fagin, T. V. Petrovskaya, J. W. Ziller, R. N. R. Broomhall-Dillard, W. J. Evans, Angew. Chem. Int. Ed. Engl. 1997, 36, 133–135; Angew. Chem. 1997, 109, 123–124.
- 8F. Nief, Dalton Trans. 2010, 39, 6589–6598.
- 9E. Prasad, B. W. Knettle, R. A. Flowers, J. Am. Chem. Soc. 2002, 124, 14663–14667.
- 10A. Momin, F. Bonnet, M. Visseaux, L. Maron, J. Takats, M. J. Ferguson, X.-F. Le Goff, F. Nief, Chem. Commun. 2011, 47, 12203–12205.
- 11
- 11aS. Labouille, C. Clavaguera, F. Nief, Organometallics 2013, 32, 1265–1271;
- 11bG. Nocton, L. Ricard, Dalton Trans. 2014, 43, 4380–4387.
- 12
- 12aW. J. Evans, Organometallics 2016, 35, 3088–3100;
- 12bM. E. Fieser, M. R. MacDonald, B. T. Krull, J. E. Bates, J. W. Ziller, F. Furche, W. J. Evans, J. Am. Chem. Soc. 2015, 137, 369–382.
- 13L. R. Morss, Chem. Rev. 1976, 76, 827–841.
- 14G.-L. Law, T. A. Pham, J. Xu, K. N. Raymond, Angew. Chem. Int. Ed. 2012, 51, 2371–2374; Angew. Chem. 2012, 124, 2421–2424.
- 15
- 15aJ. D. Rinehart, J. R. Long, Chem. Sci. 2011, 2, 2078–2085;
- 15bD. N. Woodruff, R. E. P. Winpenny, R. A. Layfield, Chem. Rev. 2013, 113, 5110–5148;
- 15cH. L. C. Feltham, S. Brooker, Coord. Chem. Rev. 2014, 276, 1–43;
- 15dP. Zhang, Y.-N. Guo, J. Tang, Coord. Chem. Rev. 2013, 257, 1728–1763;
- 15eF. Pointillart, O. Cador, B. Le Guennic, L. Ouahab, Coord. Chem. Rev. 2017, DOI: 10.1016/j.ccr.2016.12.017.
- 16K. R. Meihaus, M. E. Fieser, J. F. Corbey, W. J. Evans, J. R. Long, J. Am. Chem. Soc. 2015, 137, 9855–9860.
- 17
- 17aJ. D. Rinehart, M. Fang, W. J. Evans, J. R. Long, Nat. Chem. 2011, 3, 538–542;
- 17bJ. D. Rinehart, M. Fang, W. J. Evans, J. R. Long, J. Am. Chem. Soc. 2011, 133, 14236–14239.
- 18
- 18aC. H. Booth, M. D. Walter, M. Daniel, W. W. Lukens, R. A. Andersen, Phys. Rev. Lett. 2005, 95, 267202;
- 18bC. H. Booth, M. D. Walter, D. Kazhdan, Y.-J. Hu, W. W. Lukens, E. D. Bauer, L. Maron, O. Eisenstein, R. A. Andersen, J. Am. Chem. Soc. 2009, 131, 6480–6491;
- 18cM. D. Walter, C. H. Booth, W. W. Lukens, R. A. Andersen, Organometallics 2009, 28, 698–707;
- 18dC. H. Booth, D. Kazhdan, E. L. Werkema, M. D. Walter, W. W. Lukens, E. D. Bauer, Y.-J. Hu, L. Maron, O. Eisenstein, M. Head-Gordon, R. A. Andersen, J. Am. Chem. Soc. 2010, 132, 17537–17549.
- 19M. R. MacDonald, J. E. Bates, M. E. Fieser, J. W. Ziller, F. Furche, W. J. Evans, J. Am. Chem. Soc. 2012, 134, 8420–8423.
- 20E. L. Muetterties, L. J. Guggenberger, J. Am. Chem. Soc. 1974, 96, 1748–1756.
- 21
- 21aJ.-C. G. Bünzli, S. V. Eliseeva, J. Rare Earths 2010, 28, 824–842;
- 21bJ.-C. G. Bünzli, A.-S. Chauvin, H. K. Kim, E. Deiters, S. V. Eliseeva, Coord. Chem. Rev. 2010, 254, 2623–2633.
- 22J. Grimm, E. Beurer, H. U. Güdel, Inorg. Chem. 2006, 45, 10905–10908.
- 23
- 23aZ. J. Kiss, Phys. Rev. 1962, 127, 718–724;
- 23bJ. Grimm, O. S. Wenger, K. W. Krämer, H. U. Güdel, J. Lumin. 2007, 126, 590–596.
- 24W. J. Schipper, A. Meijerink, G. Blasse, J. Lumin. 1994, 62, 55–59.
- 25J. Grimm, J. F. Suyver, E. Beurer, G. Carver, H. U. Güdel, J. Phys. Chem. B 2006, 110, 2093–2101.
- 26
- 26aE. Beurer, J. Grimm, P. Gerner, H. U. Güdel, J. Am. Chem. Soc. 2006, 128, 3110–3111;
- 26bO. M. ten Kate, K. W. Krämer, E. van der Kolk, Sol. Energy Mater. Sol. Cells 2015, 140, 115–120.
- 27X. Yi, K. Bernot, V. Le Corre, G. Calvez, F. Pointillart, O. Cador, B. Le Guennic, J. Jung, O. Maury, V. Placide, Y. Guyot, T. Roisnel, C. Daiguebonne, O. Guillou, Chem. Eur. J. 2014, 20, 1569–1576.
- 28C. Benelli, D. Gatteschi, Introduction to Molecular Magnetism, Wiley-VCH, Weinheim, 2015.
10.1002/9783527690541 Google Scholar
- 29C. A. P. Goodwin, N. F. Chilton, G. F. Vettese, E. Moreno Pineda, I. F. Crowe, J. W. Ziller, R. E. P. Winpenny, W. J. Evans, D. P. Mills, Inorg. Chem. 2016, 55, 10057–10067.
- 30R. G. Denning, J. Harmer, J. C. Green, M. Irwin, J. Am. Chem. Soc. 2011, 133, 20644–20660.
- 31A. Belio Castro, J. Jung, S. Golhen, B. Le Guennic, L. Ouahab, O. Cador, F. Pointillart, Magnetochemistry 2016, 2, 26.
- 32J. Jung, F. Le Natur, O. Cador, F. Pointillart, G. Calvez, C. Daiguebonne, O. Guillou, T. Guizouarn, B. Le Guennic, K. Bernot, Chem. Commun. 2014, 50, 13346.
- 33
- 33aK. S. Pedersen, A.-M. Aricius, S. McAdams, H. Weihe, J. Bendix, F. Tuna, S. Piligkos, J. Am. Chem. Soc. 2016, 138, 5801–5804;
- 33bJ. Liu, Y.-C. Chen, J.-L. Liu, V. Vieru, L. Ungur, J.-H. Jia, L. F. Chibotaru, Y. Lan, W. Wernsdorfer, S. Gao, X.-M. Chen, M.-L. Tong, J. Am. Chem. Soc. 2016, 138, 5441–5450.
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