Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO2
Dr. Kai-Jie Chen
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorDr. David G. Madden
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Tony Pham
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., CHE205, Tampa, FL, 33620-5250 USA
Search for more papers by this authorKatherine A. Forrest
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., CHE205, Tampa, FL, 33620-5250 USA
Search for more papers by this authorAmrit Kumar
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Qing-Yuan Yang
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Wei Xue
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorProf. Dr. Brian Space
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., CHE205, Tampa, FL, 33620-5250 USA
Search for more papers by this authorDr. John J. Perry IV
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorCorresponding Author
Prof. Dr. Jie-Peng Zhang
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorProf. Dr. Xiao-Ming Chen
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Michael J. Zaworotko
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Kai-Jie Chen
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorDr. David G. Madden
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Tony Pham
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., CHE205, Tampa, FL, 33620-5250 USA
Search for more papers by this authorKatherine A. Forrest
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., CHE205, Tampa, FL, 33620-5250 USA
Search for more papers by this authorAmrit Kumar
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Qing-Yuan Yang
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorDr. Wei Xue
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorProf. Dr. Brian Space
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., CHE205, Tampa, FL, 33620-5250 USA
Search for more papers by this authorDr. John J. Perry IV
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorCorresponding Author
Prof. Dr. Jie-Peng Zhang
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorProf. Dr. Xiao-Ming Chen
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275 P.R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Michael J. Zaworotko
Department of Chemical & Environmental Sciences, Bernal Institute, University of Limerick, Plassey House, Limerick, Republic of Ireland
Search for more papers by this authorAbstract
Porous materials capable of selectively capturing CO2 from flue-gases or natural gas are of interest in terms of rising atmospheric CO2 levels and methane purification. Size-exclusive sieving of CO2 over CH4 and N2 has rarely been achieved. Herein we show that a crystal engineering approach to tuning of pore-size in a coordination network, [Cu(quinoline-5-carboxyate)2]n (Qc-5-Cu) ena+bles ultra-high selectivity for CO2 over N2 (SCN≈40 000) and CH4 (SCM≈3300). Qc-5-Cu-sql-β, a narrow pore polymorph of the square lattice (sql) coordination network Qc-5-Cu-sql-α, adsorbs CO2 while excluding both CH4 and N2. Experimental measurements and molecular modeling validate and explain the performance. Qc-5-Cu-sql-β is stable to moisture and its separation performance is unaffected by humidity.
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