β-Ag3RuO4, a Ruthenate(V) Featuring Spin Tetramers on a Two-Dimensional Trigonal Lattice
Dr. Beluvalli E. Prasad
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Search for more papers by this authorProf. Pavel Kazin
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Department of Chemistry, Moscow State University, 119991 Moscow, Russia
Search for more papers by this authorDr. Alexander C. Komarek
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Search for more papers by this authorProf. Dr. Claudia Felser
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Martin Jansen
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Max-Planck-Institut für Festkörperforschung, 70569 Stuttgart, Germany
Search for more papers by this authorDr. Beluvalli E. Prasad
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Search for more papers by this authorProf. Pavel Kazin
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Department of Chemistry, Moscow State University, 119991 Moscow, Russia
Search for more papers by this authorDr. Alexander C. Komarek
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Search for more papers by this authorProf. Dr. Claudia Felser
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Martin Jansen
Max-Planck-Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany
Max-Planck-Institut für Festkörperforschung, 70569 Stuttgart, Germany
Search for more papers by this authorAbstract
Open-shell solids exhibit a plethora of intriguing physical phenomena that arise from a complex interplay of charge, spin, orbital, and spin-state degrees of freedom. Comprehending these phenomena is an indispensable prerequisite for developing improved functional materials. This type of understanding can be achieved, on the one hand, by experimental and theoretical investigations into known systems, or by synthesizing new solids displaying unprecedented structural and/or electronic features. β-Ag3RuO4 may serve as such a model system because it possesses a remarkable anionic structure, consisting of tetrameric polyoxoanions (Ru4O16)12−, and is an embedded fragment of a 2D trigonal MO2 lattice. The notorious frustration of antiferromagnetic (AF) exchange couplings on such lattices is thus lifted, and instead strong AF occurs within the oligomeric anion, where only one exchange path remains frustrated among the relevant six. The strong magnetic anisotropy of the [Ru4O16]12− ion, and the effectively orbital nature of its net magnetic moment, implies that this anion may reveal the properties of a single-molecule magnet if well-diluted in a diamagnetic matrix.
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