Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes
Ge Zhang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
These authors contributed equally to this work.
Search for more papers by this authorProf. Tao Xiong
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
These authors contributed equally to this work.
Search for more papers by this authorZining Wang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Search for more papers by this authorGuoxing Xu
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Search for more papers by this authorXuedan Wang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Search for more papers by this authorCorresponding Author
Prof. Qian Zhang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)Search for more papers by this authorGe Zhang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
These authors contributed equally to this work.
Search for more papers by this authorProf. Tao Xiong
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
These authors contributed equally to this work.
Search for more papers by this authorZining Wang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Search for more papers by this authorGuoxing Xu
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Search for more papers by this authorXuedan Wang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Search for more papers by this authorCorresponding Author
Prof. Qian Zhang
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)
Department of Chemistry, Northeast Normal University, Changchun, 130024 (China)Search for more papers by this authorAbstract
The first controllable, regioselective radical amination of allenes with N-fluoroarylsulfonimide is described to proceed under very mild reaction conditions. With this methodology, a general and straightforward route for the synthesis of both allenamides and fluorinated tetrasubstituted alkenes was realized from a wide range of terminal and internal allenes.
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