Direct X-Ray Scattering Evidence for Metal–Metal Interactions in Solution at the Molecular Level
Andrea Cebollada
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Visiting scholar at Oregon State University.
Search for more papers by this authorAlba Vellé
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorDr. Manuel Iglesias
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorLauren B. Fullmer
Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Search for more papers by this authorDr. Sara Goberna-Ferrón
Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Search for more papers by this authorCorresponding Author
Dr. May Nyman
Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
May Nyman, Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Pablo J. Sanz Miguel, Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorCorresponding Author
Dr. Pablo J. Sanz Miguel
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
May Nyman, Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Pablo J. Sanz Miguel, Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorAndrea Cebollada
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Visiting scholar at Oregon State University.
Search for more papers by this authorAlba Vellé
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorDr. Manuel Iglesias
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorLauren B. Fullmer
Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Search for more papers by this authorDr. Sara Goberna-Ferrón
Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Search for more papers by this authorCorresponding Author
Dr. May Nyman
Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
May Nyman, Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Pablo J. Sanz Miguel, Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorCorresponding Author
Dr. Pablo J. Sanz Miguel
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
May Nyman, Center for Sustainable Materials Chemistry, Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003 (USA)
Pablo J. Sanz Miguel, Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza (Spain)
Search for more papers by this authorAbstract
The study of the aggregation of small molecules in solution induced by metallophilic interactions has been traditionally performed by spectroscopic methods through identification of chemical changes in the system. Herein we demonstrate the use of SAXS (small-angle X-ray scattering) to identify structures in solution, taking advantage of the excellent scattering intensity of heavy metals which have undergone association by metallophilic interactions. An analysis of the close relationship between solid-state and solution arrangements of a dynamic [Ag2(bisNHC)2]2+ (NHC=N-heterocyclic carbene) system, and how they are complementary to each other, is reported.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange_201505736_sm_miscellaneous_information.pdf1,003.3 KB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aM. Jansen, Angew. Chem. Int. Ed. Engl. 1987, 26, 1098–1110; Angew. Chem. 1987, 99, 1136–1149;
- 1bP. Pyykkö, Chem. Rev. 1997, 97, 597–636;
- 1cH. Schmidbaur, Gold Bull. 2000, 33, 3–10;
- 1dH. Schmidbaur, Nature 2001, 413, 31–33.
- 2
- 2aT. Osuga, T. Murase, M. Fujita, Angew. Chem. Int. Ed. 2012, 51, 12199–12201; Angew. Chem. 2012, 124, 12365–12367;
- 2bY. Kohyama, T. Murase, M. Fujita, Angew. Chem. Int. Ed. 2014, 53, 11510–11513; Angew. Chem. 2014, 126, 11694–11697;
- 2cT. Sawada, A. Matsumoto, M. Fujita, Angew. Chem. Int. Ed. 2014, 53, 7228–7232; Angew. Chem. 2014, 126, 7356–7360;
- 2dA. Rit, T. Pape, F. E. Hahn, J. Am. Chem. Soc. 2010, 132, 4572–4573;
- 2eX.-P. Zhou, Y. Wu, D. Li, J. Am. Chem. Soc. 2013, 135, 16062–16065;
- 2fC.-Y. Gao, L. Zhao, M.-X. Wang, J. Am. Chem. Soc. 2012, 134, 824–827;
- 2gA. Vellé, A. Cebollada, M. Iglesias, P. J. Sanz Miguel, Inorg. Chem. 2014, 53, 10654–10659.
- 3See, for example:
- 3aA. Desireddy, B. E. Conn, J. Guo, B. Yoon, R. N. Barnett, B. M. Monahan, K. Kirschbaum, W. P. Griffith, R. L. Whetten, U. Landman, T. P. Bigioni, Nature 2013, 501, 399–402;
- 3bX. He, X.-B. Xu, X. Wanga, L. Zhao, Chem. Commun. 2013, 49, 7153–7155;
- 3cY. Yao, K. Jie, Y. Zhou, M. Xue, Chem. Commun. 2014, 50, 5072–5074.
- 4
- 4aK. M. Hutchins, T. P. Rupasinghe, L. R. Ditzler, D. C. Swenson, J. R. G. Sander, J. Baltrusaitis, A. V. Tivanski, L. R. MacGillivray, J. Am. Chem. Soc. 2014, 136, 6778–6781;
- 4bS. L. Zheng, J. P. Zhang, W. T. Wong, X. M. Chen, J. Am. Chem. Soc. 2003, 125, 6882–6883.
- 5
- 5aY. Morishima, D. J. Young, K. Fujisawa, Dalton Trans. 2014, 43, 15915–15928;
- 5bJ. Zheng, Y.-D. Yu, F.-F. Liu, B.-Y. Liu, G. Wei, X.-C. Huang, Chem. Commun. 2014, 50, 9000–9002;
- 5cA. A. Mohamed, A. Burini, J. P. Fackler, J. Am. Chem. Soc. 2005, 127, 5012–5013.
- 6
- 6aW. Cai, A. Katrusiak, Nat. Commun. 2014, 5, 4337;
- 6bM. A. Sinnwell, J. Baltrusaitis, L. R. MacGillivray, Cryst. Growth Des. 2015, 15, 538–541;
- 6cQ. Chu, D. C. Swenson, L. R. MacGillivray, Angew. Chem. Int. Ed. 2005, 44, 3569–3572; Angew. Chem. 2005, 117, 3635–3638;
- 6dT. Osuga, T. Murase, M. Hoshino, M. Fujita, Angew. Chem. Int. Ed. 2014, 53, 11186–11189; Angew. Chem. 2014, 126, 11368–11371;
- 6eC.-Y. Gao, L. Zhao, M.-X. Wang, J. Am. Chem. Soc. 2011, 133, 8448–8451.
- 7For a recent review, see: H. Schmidbaur, A. Schier, Angew. Chem. Int. Ed. 2015, 54, 746–784; Angew. Chem. 2015, 127, 756–797 and references therein.
- 8C. D. Putnam, M. Hammel, G. L. Hura, J. A. Tainer, Q. Rev. Biophys. 2007, 40, 191–285.
- 9
- 9aR. E. Ruther, B. M. Baker, J.-H. Son, W. H. Casey, M. Nyman, Inorg. Chem. 2014, 53, 4234–4242;
- 9bD. Gebauer, H. Cölfen, Nano Today 2011, 6, 564–584.
- 10
- 10aO. Sadeghi, L. N. Zakharov, M. Nyman, Science 2015, 347, 1359–1362;
- 10bY. Hou, L. N. Zakharov, M. Nyman, J. Am. Chem. Soc. 2013, 135, 16651–16657.
- 11
- 11aH. Borchert, E. V. Shevchenko, A. Robert, I. Mekis, A. Kornowski, G. Grübel, H. Weller, Langmuir 2005, 21, 1931–1936;
- 11bJ. Polte, T. T. Ahner, F. Delissen, S. Sokolov, F. Emmerling, A. F. Thünemann, R. Kraehnert, J. Am. Chem. Soc. 2010, 132, 1296–1301.
- 12W. Gamrad, A. Dreier, R. Goddard, K.-R. Pörschke, Angew. Chem. Int. Ed. 2015, 54, 4482–4487; Angew. Chem. 2015, 127, 4564–4569 and references therein.
- 13S. Johannsen, N. Megger, N. Böhme, R. K. O. Sigel, J. Müller, Nat. Chem. 2010, 2, 229–234.
- 14For a hexafluorophosphate salt of 2 a, see: C. A. Quezada, J. C. Garrison, M. J. Panzner, C. A. Tessier, W. J. Youngs, Organometallics 2004, 23, 4846–4848.
- 15M. Kriechbaum, J. Hölbling, H.-G. Stammler, M. List, R. J. F. Berger, U. Monkowius, Organometallics 2013, 32, 2876–2884.
- 16A. Guinier, G. Fournet, Small-Angle Scattering of X-Rays, Wiley, New York, 1955.
- 17B. Moore, J. Appl. Crystallogr. 1980, 13, 168–175.
- 18R. T. Zhang, P. Thiyagarajan, D. M. Tiede, J. Appl. Crystallogr. 2000, 33, 565–568.
- 19CCDC 1406442 (1 a), 1406443 (2 a), and 1406444 (2 b) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
