Clicked Isoreticular Metal–Organic Frameworks and Their High Performance in the Selective Capture and Separation of Large Organic Molecules
Dr. Pei-Zhou Li
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
These authors contributed equally.
Search for more papers by this authorDr. Xiao-Jun Wang
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
These authors contributed equally.
Search for more papers by this authorSi Yu Tan
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
These authors contributed equally.
Search for more papers by this authorChung Yen Ang
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorHongzhong Chen
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorDr. Jia Liu
Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ruqiang Zou
Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
Ruqiang Zou, Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Yanli Zhao, Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yanli Zhao
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore)
Ruqiang Zou, Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Yanli Zhao, Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorDr. Pei-Zhou Li
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
These authors contributed equally.
Search for more papers by this authorDr. Xiao-Jun Wang
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
These authors contributed equally.
Search for more papers by this authorSi Yu Tan
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
These authors contributed equally.
Search for more papers by this authorChung Yen Ang
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorHongzhong Chen
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorDr. Jia Liu
Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ruqiang Zou
Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
Ruqiang Zou, Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Yanli Zhao, Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yanli Zhao
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Singapore Peking University Research Centre (SPURc) for a Sustainable Low-Carbon Future, 1 Create Way, 138602 (Singapore)
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore)
Ruqiang Zou, Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China)
Yanli Zhao, Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 (Singapore)
Search for more papers by this authorAbstract
Three highly porous metal–organic frameworks (MOFs) with a uniform rht-type topological network but hierarchical pores were successfully constructed by the assembly of triazole-containing dendritic hexacarboxylate ligands with ZnII ions. These transparent MOF crystals present gradually increasing pore sizes upon extension of the length of the organic backbone, as clearly identified by structural analysis and gas-adsorption experiments. The inherent accessibility of the pores to large molecules endows these materials with unique properties for the uptake of large guest molecules. The visible selective adsorption of dye molecules makes these MOFs highly promising porous materials for pore-size-dependent large-molecule capture and separation.
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