Highly Efficient Enrichment of Volatile Iodine by Charged Porous Aromatic Frameworks with Three Sorption Sites
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Addendum: Highly Efficient Enrichment of Volatile Iodine by Charged Porous Aromatic Frameworks with Three Sorption Sites
- Volume 127Issue 48Angewandte Chemie
- pages: 14422-14422
- First Published online: November 18, 2015
Dr. Zhuojun Yan
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin UniversityChangchun, Jilin 130012 (P.R. China)
Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan, Queensland, 4111 (Australia)
These authors contributed equally to this work.
Search for more papers by this authorDr. Ye Yuan
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
These authors contributed equally to this work.
Search for more papers by this authorDr. Yuyang Tian
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
Search for more papers by this authorProf. Daming Zhang
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin UniversityChangchun, Jilin 130012 (P.R. China)
Search for more papers by this authorCorresponding Author
Prof. Guangshan Zhu
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)Search for more papers by this authorDr. Zhuojun Yan
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin UniversityChangchun, Jilin 130012 (P.R. China)
Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan, Queensland, 4111 (Australia)
These authors contributed equally to this work.
Search for more papers by this authorDr. Ye Yuan
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
These authors contributed equally to this work.
Search for more papers by this authorDr. Yuyang Tian
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
Search for more papers by this authorProf. Daming Zhang
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin UniversityChangchun, Jilin 130012 (P.R. China)
Search for more papers by this authorCorresponding Author
Prof. Guangshan Zhu
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)
Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (P.R. China)Search for more papers by this authorAbstract
The targeted synthesis of a series of novel charged porous aromatic frameworks (PAFs) is reported. The compounds PAF-23, PAF-24, and PAF-25 are built up by a tetrahedral building unit, lithium tetrakis(4-iodophenyl)borate (LTIPB), and different alkyne monomers as linkers by a Sonogashira–Hagihara coupling reaction. They possess excellent adsorption properties to organic molecules owing to their “breathing” dynamic frameworks. As these PAF materials assemble three effective sorption sites, namely the ion bond, phenyl ring, and triple bond together, they exhibit high affinity and capacity for iodine molecules. To the best of our knowledge, these PAF materials give the highest adsorption values among all porous materials (zeolites, metal–organic frameworks, and porous organic frameworks) reported to date.
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