Wet-Chemical Synthesis of Phase-Pure FeOF Nanorods as High-Capacity Cathodes for Sodium-Ion Batteries†
Jian Zhu
Department of Chemical Engineering and Materials Science, Wayne State University, 5050 Anthony Wayne Drive, Detroit, MI 48202 (USA)
Search for more papers by this authorCorresponding Author
Dr. Da Deng
Department of Chemical Engineering and Materials Science, Wayne State University, 5050 Anthony Wayne Drive, Detroit, MI 48202 (USA)
Department of Chemical Engineering and Materials Science, Wayne State University, 5050 Anthony Wayne Drive, Detroit, MI 48202 (USA)Search for more papers by this authorJian Zhu
Department of Chemical Engineering and Materials Science, Wayne State University, 5050 Anthony Wayne Drive, Detroit, MI 48202 (USA)
Search for more papers by this authorCorresponding Author
Dr. Da Deng
Department of Chemical Engineering and Materials Science, Wayne State University, 5050 Anthony Wayne Drive, Detroit, MI 48202 (USA)
Department of Chemical Engineering and Materials Science, Wayne State University, 5050 Anthony Wayne Drive, Detroit, MI 48202 (USA)Search for more papers by this authorWe thank the Lumigen Instrument Center, Wayne State University.
Abstract
It is challenging to prepare phase-pure FeOF by wet-chemical methods. Furthermore, nanostructured FeOF has never been reported. In this study, hierarchical FeOF nanorods were synthesized through a facile, one-step, wet-chemical method by the use of just FeF3⋅3H2O and an alcohol. It was possible to significantly control the FeOF nanostructure by the selection of alcohols with an appropriate molecular structure. A mechanism for the formation of the nanorods is proposed. An impressive high specific capacity of approximately 250 mAh g−1 and excellent cycling and rate performances were demonstrated for sodium storage. The hierarchical FeOF nanorods are promising high-capacity cathodes for SIBs.
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