Synthesis of Air-Stable, Volatile Uranium(IV) and (VI) Compounds and Their Gas-Phase Conversion To Uranium Oxide Films†
Linus Appel
Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorJennifer Leduc
Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorChristopher L. Webster
Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Search for more papers by this authorDr. Joseph W. Ziller
Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. William J. Evans
Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
William J. Evans, Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Sanjay Mathur, Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Sanjay Mathur
Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
William J. Evans, Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Sanjay Mathur, Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorLinus Appel
Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorJennifer Leduc
Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorChristopher L. Webster
Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Search for more papers by this authorDr. Joseph W. Ziller
Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. William J. Evans
Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
William J. Evans, Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Sanjay Mathur, Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Sanjay Mathur
Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
William J. Evans, Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA)
Sanjay Mathur, Department of Materials and Inorganic Chemistry, University of Cologne, Greinstr. 6, 50939 Cologne (Germany)
Search for more papers by this authorWe thank the Chemical Sciences, Geosciences, and Biosciences Division of the Office of Basic Energy Sciences of the Department of Energy (DE-SC0004739) for support (to W.J.E.) and the University of Cologne, especially Prof. Gerd Meyer, for providing financial assistance. We thank Astrid Baum for measurements of the EI-MS spectra.
Abstract
Four air-stable, volatile uranium heteroarylalkenolates have been synthesized and characterized by three synthetic approaches and their gas phase deposition to uranium oxide films has been examined.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange_201409606_sm_miscellaneous_information.pdf800.2 KB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aH. Gilman, R. G. Jones, E. Bindschadler, D. Blume, G. Karmas, G. A. Martin, Jr., J. F. Nobis, H. L. Yale, F. A. Yoeman, J. Am. Chem. Soc. 1956, 78, 2790;
- 1bR. G. Jones, G. Karmas, G. A. Martin, Jr., H. Gilman, J. Am. Chem. Soc. 1956, 78, 4285;
- 1cR. G. Jones, E. Bindschadler, G. Karmas, F. A. Yoeman, H. Gliman, J. Am. Chem. Soc. 1956, 78, 4287;
- 1dR. G. Jones, E. Binschadler, G. Karmas, G. A. Martin, Jr., J. R. Thirtle, F. A. Yoeman, H. Gilman, J. Am. Chem. Soc. 1956, 78, 4289;
- 1eR. G. Jones, E. Binschadler, D. Blume, G. Karmas, G. A. Martin, Jr., J. R. Thirtle, H. Gilman, J. Am. Chem. Soc. 1956, 78, 6027;
- 1fR. G. Jones, E. Binschadler, D. Blume, G. Karmas, G. A. Martin, Jr., J. R. Thirtle, F. A. Yoeman, H. Gilman, J. Am. Chem. Soc. 1956, 78, 6030;
- 1gR. G. Jones, E. Bindschadler, G. A. Martin, Jr., J. R. Thirtle, H. Gilman, J. Am. Chem. Soc. 1957, 79, 4921;
- 1hH. I. Schlesinger, H. C. Brown, B. Abraham, A. C. Bond, N. Davidson, A. E. Finhol. t, J. R. Gilbreath, H. Hoekstra, L. Horvitz, E. K. Hyde, J. J. Katz, J. Knight, R. A. Lad, D. L. Mayfield, L. Rapp, D. M. Ritter, A. M. Schwartz, I. Sheft, L. D. Tuck, A. O. Walker, J. Am. Chem. Soc. 1953, 75, 186.
- 2
- 2aD. C. Bradley, B. N. Chakravarti, A. K. Chatterjee, J. Inorg. Nucl. Chem. 1957, 3, 367;
- 2bD. C. Bradley, A. K. Chatterjee, J. Inorg. Nucl. Chem. 1957, 4, 279;
- 2cD. C. Bradley, R. N. Kapoor, B. C. Smith, J. Chem. Soc. 1963, 1023;
- 2dD. C. Bradley, A. K. Chatterjee, A. K. Chatterjee, J. Inorg. Nucl. Chem. 1959, 12, 71;
- 2eD. C. Bradley, R. N. Kapoor, B. C. Smith, J. Inorg. Nucl. Chem. 1962, 24, 863;
- 2fD. C. Bradley, R. N. Kapoor, B. C. Smith, J. Chem. Soc. 1963, 204.
- 3W. G. Van Der Sluys, A. P. Sattelberger, Chem. Rev. 1990, 90, 1027.
- 4E. Jacob, Angew. Chem. Int. Ed. Engl. 1982, 21, 142; Angew. Chem. 1982, 94, 146.
- 5
- 5aP. J. Vergamini, J. Chem. Soc. Chem. Commun. 1979, 54;
- 5bE. A. Cuellar, T. J. Marks, Inorg. Chem. 1981, 20, 2129;
- 5cE. A. Cuellar, S. S. Miller, T. J. Marks, E. Weitz, J. Am. Chem. Soc. 1983, 105, 4580.
- 6
- 6aM. R. MacDonald, M. E. Fieser, J. E. Bates, J. W. Ziller, F. Furche, W. J. Evans, J. Am. Chem. Soc. 2013, 135, 13310;
- 6bH. S. La Pierre, A. Scheurer, F. W. Heineman, W. Hieringer, K. Meyer, Angew. Chem. Int. Ed. 2014, 53, 7158; Angew. Chem. 2014, 126, 7286.
- 7
- 7aD. M. King, S. T. Liddle, Coord. Chem. Rev. 2014, 266–267, 2;
- 7bD. M. Ing, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Nat. Chem. 2013, 5, 482;
- 7cS. M. Mansell, N. Kaltsoyannis, P. L. Arnold, J. Am. Chem. Soc. 2011, 133, 9036;
- 7dP. L. Arnold, Z. R. Turner, R. M. Bellabarba, R. P. Tooze, Chem. Sci. 2011, 2, 77;
- 7eA. S. P. Frey, F. G. N. Cloke, M. P. Coles, L. Maron, T. Davin, Angew. Chem. Int. Ed. 2011, 50, 6881; Angew. Chem. 2011, 123, 7013.
- 8
- 8aM. Ephritikhine, Organometallics 2013, 32, 2464;
- 8bS. C. Bart, C. Anthon, F. W. Heinemann, E. Bill, N. M. Edelstein, K. Meyer, J. Am. Chem. Soc. 2008, 130, 12536;
- 8cO. Cooper, C. Camp, J. Pécaut, C. E. Kafalidis, L. Maron, S. Gambarelli, M. Mazzanti, J. Am. Chem. Soc. 2014, 136, 6716.
- 9Y. Shiokawa, R. Amano, A. Nomura, M. Yagi, J. Radioanal. Nucl. Chem. 1991, 152, 373.
- 10M. Veith, S. Mathur, C. Mathur, Polyhedron 1998, 17, 1005.
- 11
- 11aL. Appel, R. Fiz, W. Tyrra, S. Mathur, Dalton Trans. 2012, 41, 1981;
- 11bL. Appel, R. Fiz, W. Tyrra, I. Pantenburg, Eur. J. Inorg. Chem. 2014, submitted;
- 11cL. Brückmann, W. Tyrra, S. Stucky, S. Mathur, Inorg. Chem. 2012, 51, 536;
- 11dT. Lehnen, J. Schläfer, S. Mathur, Z. Anorg. Allg. Chem. 2014, 640, 819.
- 12
- 12aT. F. McGrath, R. Levine, J. Am. Chem. Soc. 1955, 77, 3656;
- 12bC. A. Root, J. E. Rowe, Jr., H. Veending, Inorg. Chem. 1971, 10, 1195;
- 12cI. Giebelhaus, R. Müller, W. Tyrra, I. Pantenburg, T. Fischer, S. Mathur, Inorg. Chim. Acta 2011, 372, 340;
- 12dL. Brückmann, W. Tyrra, S. Mathur, G. Berden, J. Oomens, A. J. H. M. Meijer, M. Schäfer, ChemPhysChem 2012, 13, 2037;
- 12eL. Czympiel, W. Tyrra, J. Pfrommer, M. Schäfer, S. Mathur, Inorg. Chem., DOI: ;
- 12fG. Fornalczyk, M. Valldor, S. Mathur, Cryst. Growth Des. 2014, 14, 1811.
- 13R. E. Sievers, J. E. Sadlowski, Science 1978, 201, 217.
- 14
- 14aD. Bodansky, Nuclear Energy: Principles, Practices, and Prospects, 2nd ed., Springer, New York, 2004;
- 14bM. J. Monreal, P. L. Diaconescu, Nat. Chem. 2010, 2, 424.
- 15
- 15aD. Hudry, C. Apostolidis, O. Walter, T. Gouder, E. Courtois, C. Kübel, D. Meyer, Chem. Eur. J. 2012, 18, 8283;
- 15bX.-D. Wen, R. L. Martin, T. M. Henderson, G. E. Scuseria, Chem. Rev. 2013, 113, 1063;
- 15cC. E. Zvoriste-Walters, S. Heathman, R. Jovani-Abril, J. L. Spino, A. Janssen, R. Caciuffo, J. Nucl. Mater. 2013, 435, 123;
- 15dC. Walther, M. A. Denecke, Chem. Rev. 2013, 113, 995;
- 15eT. T. Meek, B. von Roedern, P. G. Clem, R. J. Hannrahan, Jr., Mater. Lett. 2005, 59, 1085;
- 15fT. M. Nenoff, B. W. Jacobs, D. B. Robinson, P. P. Provencio, J. Huang, S. Ferreia, D. J. Hanson, Chem. Mater. 2011, 23, 5185;
- 15gR. J. Abril, R. Eloirdi, D. Bouëxière, R. Malmbeck, J. Spino, J. Mater. Sci. 2011, 46, 7247;
- 15hD. Hudry, C. Apostolidis, O. Walter, T. Gouder, E. Courtois, C. Kübel, D. Meyer, Chem. Eur. J. 2013, 19, 5297;
- 15iL. Wang, R. Zhao, Z.-J. Gu, Y.-L. Zhao, Z.-F. Chai, W.-Q. Shi, Eur. J. Inorg. Chem. 2014, 1158;
- 15jR. Zjao, L. Wang, Z.-J. Gu, L. Y. Yuan, C.-L. Xiao, Y.-L. Zhao, Z.-F. Chai, W.-Q. Shi, CrystEngComm 2014, 16, 2645.
- 16
- 16aC. W. Forsberg, Nucl. Technol. 2000, 131, 337;
- 16bG. J. Hutchings, C. S. Heneghan, I. D. Hudson, S. H. Taylor, Nature 1996, 384, 341;
- 16cZ. R. Ismagilov, S. V. Lazareva, Catal. Rev. Sci. Eng. 2013, 55, 135;
- 16dP. Ruello, G. Petot-Ervas, C. Petot, L. Desgranges, J. Am. Ceram. Soc. 2005, 88, 604;
- 16eH. Wu, Y. Yang, Y. C. Cao, J. Am. Chem. Soc. 2006, 128, 16522;
- 16fC. S. Heneghan, G. J. Hutchings, S. R. O’Leary, S. H. Taylor, V. J. Boyd, I. D. Hudson, Catal. Today 1999, 54, 3;
- 16gS. V. Chong, M. A. Barteau, H. Idriss, Catal. Today 2000, 63, 283;
- 16hS. H. Taylor, S. R. O’Leary, Appl. Catal. B 2000, 25, 137;
- 16iA. R. Fox, S. C. Bart, K. Meyer, C. C. Cummins, Nature 2008, 455, 341;
- 16jM. Pradhan, S. Sarkar, A. K. Sinha, M. Basu, T. Pal, CrystEngComm 2011, 13, 2878;
- 16kH. Kim, M. H. Kim, M. Kaviany, J. Appl. Phys. 2014, 115, 123510.
- 17
- 17aY. Q. An, A. J. Taylor, S. D. Conradson, S. A. Trugman, T. Durakiewicz, G. Rodriguez, Phys. Rev. Lett. 2011, 106, 207402;
- 17bT. T. Meek, B. von Roedern, Vacuum 2009, 83, 226;
- 17cR. K. Willardson, J. W. Moody, H. L. Goering, J. Inorg. Nucl. Chem. 1958, 6, 19;
- 17dP. Nagels, M. Denayer, J. Devreese, Solid State Commun. 1963, 1, 35;
- 17eH. P. Meyers, T. Jonsson, R. Westin, Solid State Commun. 1964, 2, 321;
- 17fJ. L. Bates, C. A. Hinman, T. Kawada, J. Am. Ceram. Soc. 1967, 50, 652.
- 18
- 18aF. Grønvold, J. Inorg. Nucl. Chem. 1955, 1, 357;
- 18bP. Ruello, K. D. Becker, K. Ullrich, L. Desgranges, C. Petot, G. Petot-Ervas, J. Nucl. Mater. 2004, 328, 46;
- 18cSee Ref. [16d];
- 18dA. M. Chaka, G. A. E. Oxford, J. E. Stubbs, P. J. Eng, J. R. Bargar, Comput. Theor. Chem. 2012, 987, 90;
- 18eJ. Lin, I. Dahan, B. Valderrama, M. V. Manuel, Appl. Surf. Sci. 2014, 301, 475.
- 19The potassium salts of heteroalkylalkenoles were synthesized by the reaction of potassiumhexamethyldisilazide (KHMDS) as a base with the ligand in THF. Subsequent multinuclear NMR analysis revealed that the signals had been shifted toward lower field with loss of the acidic proton. To saturate the coordination sphere of potassium the compounds were crystallized in the presence of one equivalent of 18-crown-6 ether (experimental and crystallographic data as well as a molecular structure of compound 2 can be found in SI).
- 20
- 20aC. Camp, J. Andrez, J. Pécaut, M. Mazzanti, Inorg. Chem. 2013, 52, 7078; E. M. Matson, S. R. Opperwall, P. E. Fanwick, S. C. Bart, Inorg. Chem. 2013, 52, 7295.
- 21Crystallographic data are in the Supporting Information.
- 22
- 22aM. Grdenic, Acta Crystallogr. 1959, 12, 817;
- 22bH. Titze, Acta Chem. Scand. 1970, 24, 405;
- 22cB. Allard, J. Inorg. Nucl. Chem. 1976, 38, 2109.
- 23H. Idriss, Surf. Sci. Rep. 2010, 65, 67.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
