A Tray-Shaped, PdII-Clipped Au3 Complex as a Scaffold for the Modular Assembly of [3×n] Au Ion Clusters†
Takafumi Osuga
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Takashi Murase
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Manabu Hoshino
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Makoto Fujita
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)Search for more papers by this authorTakafumi Osuga
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Takashi Murase
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Manabu Hoshino
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Makoto Fujita
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)Search for more papers by this authorThis research was supported by Grants-in-Aid for Specially Promoted Research (24000009) and for Young Scientists (A) (25708008). T.O. thanks JSPS for a Research Fellowship for Young Scientists.
Abstract
A tray-shaped PdII3AuI3 complex (1) is prepared from 3,5-bis(3-pyridyl)pyrazole by means of tricyclization with AuI followed by PdII clipping. Tray 1 is an efficient scaffold for the modular assembly of [3×n] AuI clusters. Treatment of 1 with the AuI3 tricyclic guest 2 in H2O/CH3CN (7:3) or H2O results in the selective formation of a [3×2] cluster (1⋅2) or a [3×3] cluster (1⋅2⋅1), respectively. Upon subsequent addition of AgI ions, these complexes are converted to an unprecedented Au3–Au3–Ag–Au3–Au3 metal ion cluster.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange_201404892_sm_miscellaneous_information.pdf7.9 MB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aD. Gatteschi, A. Caneschi, L. Pardi, R. Sessoli, Science 1994, 265, 1054–1058;
- 1bG. Schmid, M. Bäumle, M. Geerkens, I. Heim, C. Osemann, T. Sawitowski, Chem. Soc. Rev. 1999, 28, 179–185.
- 2
- 2aJ. Zheng, C. Zhang, R. M. Dickson, Phys. Rev. Lett. 2004, 93, 077402;
- 2bH. Tsunoyama, H. Sakurai, Y. Negishi, T. Tsukuda, J. Am. Chem. Soc. 2005, 127, 9374–9375.
- 3For selected examples of metal ion clusters, see:
- 3aK. Mashima, H. Nakano, A. Nakamura, J. Am. Chem. Soc. 1993, 115, 11632–11633;
- 3bS.-M. Peng, C.-C. Wang, Y.-L. Jang, Y.-H. Chen, F.-Y. Li, C.-Y. Mou, M.-K. Leung, J. Magn. Magn. Mater. 2000, 209, 80–83;
- 3cM. Ruben, J. Rojo, F. J. Romero-Salguero, L. H. Uppadine, J.-M. Lehn, Angew. Chem. Int. Ed. 2004, 43, 3644–3662; Angew. Chem. 2004, 116, 3728–3747;
- 3dT. Murahashi, M. Fujimoto, M. Oka, Y. Hashimoto, T. Uemura, Y. Tatsumi, Y. Nakao, A. Ikeda, S. Sakaki, H. Kurosawa, Science 2006, 313, 1104–1107;
- 3eG. H. Clever, M. Shionoya, Coord. Chem. Rev. 2010, 254, 2391–2402;
- 3fA. C. Jahnke, K. Pröpper, C. Bronner, J. Teichgräber, S. Dechert, M. John, O. S. Wenger, F. Meyer, J. Am. Chem. Soc. 2012, 134, 2938–2941.
- 4For reviews of AuI ion clusters, see:
- 4aE. J. Fernández, M. Monge in Modern Supermolecular Gold Chemistry: Gold-Metal Interactions and Applications (Ed.: ), Wiley-VCH, Weinheim, 2008, pp. 131–179;
10.1002/9783527623778.ch3 Google Scholar
- 4bH. Schmidbaur, A. Schier, Chem. Soc. Rev. 2008, 37, 1931–1951;
- 4cH. Schmidbaur, A. Schier, Chem. Soc. Rev. 2012, 41, 370–412.
- 5
- 5aT. Osuga, T. Murase, K. Ono, Y. Yamauchi, M. Fujita, J. Am. Chem. Soc. 2010, 132, 15553–15555;
- 5bT. Osuga, T. Murase, M. Fujita, Angew. Chem. Int. Ed. 2012, 51, 12199–12201; Angew. Chem. 2012, 124, 12365–12367;
- 5cM. Kiguchi, J. Inatomi, Y. Takahashi, R. Tanaka, T. Osuga, T. Murase, M. Fujita, T. Tada, S. Watanabe, Angew. Chem. Int. Ed. 2013, 52, 6202–6205; Angew. Chem. 2013, 125, 6322–6325.
- 6
- 6aF. Bonati, A. Burini, B. R. Pietroni, B. Bovio, J. Organomet. Chem. 1989, 375, 147–160;
- 6bA. A. Mohamed, J. P. Fackler, Jr., Comments Inorg. Chem. 2003, 24, 253–280.
- 7For recent syntheses of MI6 clusters (M=Au, Ag, Cu) as double-stacked MI3 complexes using bipyrazolyl ligands, see:
- 7aT. Jozak, Y. Sun, Y. Schmitt, S. Lebedkin, M. Kappes, M. Gerhards, W. R. Thiel, Chem. Eur. J. 2011, 17, 3384–3389;
- 7bG.-F. Gao, M. Li, S.-Z. Zhan, Z. Lv, G.-h. Chen, D. Li, Chem. Eur. J. 2011, 17, 4113–4117.
- 8
- 8aM. A. Omary, M. A. Rawashdeh-Omary, M. W. A. Gonser, O. Elbjeirami, T. Grimes, T. R. Cundari, Inorg. Chem. 2005, 44, 8200–8210;
- 8bL. E. Sansores, R. Salcedo, A. Martínez, N. Mireles, THEOCHEM 2006, 763, 7–11;
- 8cS. M. Tekarli, T. R. Cundari, M. A. Omary, J. Am. Chem. Soc. 2008, 130, 1669–1675.
- 9
- 9aP. Pyykkö, Chem. Rev. 1997, 97, 597–636;
- 9bC.-M. Che, S.-W. Lai, Coord. Chem. Rev. 2005, 249, 1296–1309;
- 9cE. J. Fernández, C. Hardacre, A. Laguna, M. C. Lagunas, J. M. López-de-Luzuriaga, M. Monge, M. Montiel, M. E. Olmos, R. C. Puelles, E. Sánchez-Forcada, Chem. Eur. J. 2009, 15, 6222–6233.
- 10
- 10aM. J. Katz, K. Sakai, D. B. Leznoff, Chem. Soc. Rev. 2008, 37, 1884–1895;
- 10bS. Coco, P. Espinet in Gold Chemistry: Applications and Future Directions in the Life Sciences (Ed.: ), Wiley-VCH, Weinheim, 2008, pp. 357–396.
- 11Even when an excess amount of AgNO3 was employed, no further binding of AgI ions was observed.
- 12
- 12aA. Burini, J. P. Fackler, Jr., R. Galassi, B. R. Pietroni, R. J. Staples, Chem. Commun. 1998, 95–96;
- 12bA. Kishimura, T. Yamashita, T. Aida, J. Am. Chem. Soc. 2005, 127, 179–183;
- 12cH. O. Lintang, K. Kinbara, T. Yamashita, T. Aida, Chem. Asian J. 2012, 7, 2068–2071;
- 12dW.-X. Ni, Y.-M. Qiu, M. Li, J. Zheng, R. W.-Y. Sun, S.-Z. Zhan, S. W. Ng, D. Li, J. Am. Chem. Soc. 2014, 136, 9532–9535.
- 13A. Bondi, J. Phys. Chem. 1964, 68, 441–451.
- 14G. M. Sheldrick, Acta Crystallogr. Sect. A 2008, 64, 112–122.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
