Durch Dithienylethen-Einheiten modifizierte Rubyrine†
Zhikuan Zhou
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorDr. Yi Chang
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Search for more papers by this authorDr. Soji Shimizu
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorDr. John Mack
Department of Chemistry, Rhodes University, Grahamstown (Südafrika)
Search for more papers by this authorChristian Schütt
Otto Diels-Institut für Organische Chemie, Universität Kiel (Deutschland)
Search for more papers by this authorProf. Rainer Herges
Otto Diels-Institut für Organische Chemie, Universität Kiel (Deutschland)
Search for more papers by this authorCorresponding Author
Prof. Zhen Shen
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Zhen Shen, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Nagao Kobayashi, Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Nagao Kobayashi
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Zhen Shen, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Nagao Kobayashi, Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorZhikuan Zhou
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorDr. Yi Chang
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Search for more papers by this authorDr. Soji Shimizu
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorDr. John Mack
Department of Chemistry, Rhodes University, Grahamstown (Südafrika)
Search for more papers by this authorChristian Schütt
Otto Diels-Institut für Organische Chemie, Universität Kiel (Deutschland)
Search for more papers by this authorProf. Rainer Herges
Otto Diels-Institut für Organische Chemie, Universität Kiel (Deutschland)
Search for more papers by this authorCorresponding Author
Prof. Zhen Shen
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Zhen Shen, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Nagao Kobayashi, Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Nagao Kobayashi
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Zhen Shen, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 (China)
Nagao Kobayashi, Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578 (Japan)
Search for more papers by this authorWir danken für die finanzielle Unterstützung durch das Major State Basic Research Development Program of China (Fördernr. 2013CB922101 und 2011CB808704) und die National Natural Science Foundation of China (Nr. 21371090) für Z.S. sowie für Mittel aus den Grant-in-Aids for Scientific Research on Innovative Areas (25109502, “Stimuli-responsive Chemical Species”), Scientific Research (B) (No. 23350095), and Young Scientist (B) (No. 24750031) des Ministry of Education, Culture, Sports, Science, and Technology (MEXT) von Japan. R.H. und C.S. danken für Unterstützung durch die DFG im Rahmen des SFB 677 “Funktion durch Schalten”. Die Rechnungen wurden am Centre for High Performance Computing in Kapstadt und am Otto Diels-Institut durchgeführt.
Abstract
Zwei stabile, kernmodifizierte Rubyrine mit einer oder zwei Diethienylethen(DTE)-Einheiten (1 und 2) wurden hergestellt. Das Rubyrin 1 mit einer “geschlossenen” DTE-Einheit zeigt 26 π-Aromatizität, während bei Einführung einer “offenen” DTE-Einheit in den Makrocyclus 2 dieser sich als nichtaromatische Verbindung verhält.
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