Tetrahedral Anion Cage: Self-Assembly of a (PO4)4L4 Complex from a Tris(bisurea) Ligand†
Corresponding Author
Prof. Biao Wu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)Search for more papers by this authorDr. Fengjuan Cui
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000 (China)
Search for more papers by this authorDr. Yibo Lei
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)
Search for more papers by this authorDr. Shaoguang Li
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000 (China)
Search for more papers by this authorDr. Nader de Sousa Amadeu
Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)
Search for more papers by this authorProf. Dr. Christoph Janiak
Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)
Search for more papers by this authorProf. Yue-Jian Lin
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorProf. Lin-Hong Weng
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorProf. Yao-Yu Wang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)
Search for more papers by this authorProf. Xiao-Juan Yang
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000 (China)
Search for more papers by this authorCorresponding Author
Prof. Biao Wu
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)Search for more papers by this authorDr. Fengjuan Cui
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000 (China)
Search for more papers by this authorDr. Yibo Lei
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)
Search for more papers by this authorDr. Shaoguang Li
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000 (China)
Search for more papers by this authorDr. Nader de Sousa Amadeu
Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)
Search for more papers by this authorProf. Dr. Christoph Janiak
Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)
Search for more papers by this authorProf. Yue-Jian Lin
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorProf. Lin-Hong Weng
Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai, 200433 (China)
Search for more papers by this authorProf. Yao-Yu Wang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069 (China)
Search for more papers by this authorProf. Xiao-Juan Yang
State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000 (China)
Search for more papers by this authorThis work was supported by the National Natural Science Foundation of China (Grant No. 21271149).
Graphical Abstract
Der C3-symmetrische Tris(diharnstoff)-Ligand L bildet gemeinsam mit PO43−-Ionen den tetraedrischen Käfig [(PO4)4L4]12−. Die PO43−-Ionen an den vier Ecken dieses Käfigs bilden jeweils 12 NH⋅⋅⋅O-Wasserstoffbrücken mit 6 Harnstoffgruppen. Mit SO42−-Ionen schließt sich L zu dem beispiellosen windradförmigen Dreikernkomplex [(SO4)3L2]6− zusammen (siehe Bild).
Supporting Information
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