Volume 125, Issue 8 pp. 2303-2306

Zuschrift

Pulling the Levers of Photophysics: How Structure Controls the Rate of Energy Dissipation^†

Thomas S. Kuhlman,

Thomas S. Kuhlman

Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)

Search for more papers by this author

Prof. Michael Pittelkow,

Prof. Michael Pittelkow

Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)

Search for more papers by this author

Prof. Theis I. Sølling,

Corresponding Author

Prof. Theis I. Sølling

[email protected]

Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)

Theis I. Sølling, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)===

Klaus B. Møller, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)===

Search for more papers by this author

Prof. Klaus B. Møller,

Corresponding Author

Prof. Klaus B. Møller

[email protected]

Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)

Theis I. Sølling, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)===

Klaus B. Møller, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)===

Search for more papers by this author

Thomas S. Kuhlman,

Thomas S. Kuhlman

Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)

Search for more papers by this author

Prof. Michael Pittelkow,

Prof. Michael Pittelkow

Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)

Search for more papers by this author

Prof. Theis I. Sølling,

Corresponding Author

Prof. Theis I. Sølling

[email protected]

Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)

Theis I. Sølling, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)===

Klaus B. Møller, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)===

Search for more papers by this author

Prof. Klaus B. Møller,

Corresponding Author

Prof. Klaus B. Møller

[email protected]

Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)

Theis I. Sølling, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)===

Klaus B. Møller, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)===

Search for more papers by this author

First published: 16 January 2013

https://doi.org/10.1002/ange.201208197

Citations: 2

^†

T.I.S. acknowledges the Villum foundation and M.P. acknowledges the Danish Council for Independent Research/Natural Sciences and the Lundbeck Foundation for financial support. The Danish Center for Scientific Computing (DCSC) is acknowledged for computational resources.

Share a link

Email
Wechat
Bluesky

Graphical Abstract

Interne Konversion: Der Energieunterschied zwischen der Franck-Condon- und der Gleichgewichtsgeometrie und die Schwingungsfrequenz einer oder weniger Moden legen die relative Bedeutung der adiabatischen und nicht-adiabatischen Dynamik und somit die Geschwindigkeitskonstante für die Verteilung der elektronischen Energie fest (siehe Bild). In Cycloketonen führen Veränderungen dieser Größen zu einem Unterschied in der Zeitskala des S₂→S₁-Übergangs.

Supporting Information

References

1H. Fidder, M. Rini, E. T. J. Nibbering, J. Am. Chem. Soc. 2004, 126, 3789–3794.
10.1021/ja038741y
CAS PubMed Web of Science® Google Scholar
2N. J. Turro, V. Ramamurthy, J. C. Scaiano, Modern Molecular Photochemistry of Organic Molecules, University Science Books, Sausalito, CA, 2010.
Google Scholar
3E. W.-G. Diau, J. L. Herek, Z. H. Kim, A. H. Zewail, Science 1998, 279, 847–851.
10.1126/science.279.5352.847
CAS PubMed Web of Science® Google Scholar
4O. Schalk, A. E. Boguslavskiy, A. Stolow, J. Phys. Chem. A 2010, 114, 4058–4064.
10.1021/jp911286s
CAS PubMed Web of Science® Google Scholar
5T. S. Kuhlman, W. J. Glover, T. Mori, K. B. Møller, T. J. Martínez, Faraday Discuss. 2012, 157, 193–212.
10.1039/c2fd20055d
CAS PubMed Web of Science® Google Scholar
6T. S. Kuhlman, T. I. Sølling, K. B. Møller, ChemPhysChem 2012, 13, 820–827.
10.1002/cphc.201100929
CAS PubMed Web of Science® Google Scholar
7T. S. Kuhlman, S. P. A. Sauer, T. I. Sølling, K. B. Møller, J. Chem. Phys. 2012, 137, 22A522.
10.1063/1.4742313
CAS Web of Science® Google Scholar
8T. J. Martínez, Nature 2010, 467, 412–413.
10.1038/467412a
CAS PubMed Web of Science® Google Scholar
9L. O’Toole, P. Brint, C. Kosmidis, G. Boulakis, P. Tsekeris, J. Chem. Soc. Faraday Trans. 1991, 87, 3343–3351.
10.1039/ft9918703343
CAS Web of Science® Google Scholar
10T. J. Cornish, T. Baer, J. Am. Chem. Soc. 1987, 109, 6915–6920.
10.1021/ja00257a001
CAS Web of Science® Google Scholar
11R. A. Marcus, J. Chem. Phys. 1952, 20, 359–364.
10.1063/1.1700424
CAS Web of Science® Google Scholar
12M. Bixon, J. Jortner, J. Chem. Phys. 1968, 48, 715–726.
10.1063/1.1668703
CAS Web of Science® Google Scholar
13R. Englman, J. Jortner, Mol. Phys. 1970, 18, 145–164.
10.1080/00268977000100171
CAS Web of Science® Google Scholar
14K. B. Møller, A. H. Zewail in Essays in Contemporary Chemistry: From Molecular Structure towards Biology (Eds.: ), Verlag Helvetica Chimica Acta, Zürich, and Wiley-VCH, Weinheim, 2001, chap. 5, pp. 157–188.
10.1002/9783906390451.ch5
Google Scholar

Citing Literature

Volume125, Issue8

February 18, 2013

Pages 2303-2306

This is the

German version

of Angewandte Chemie.

Note for articles published since 1962:

Do not cite this version alone.

Take me to the International Edition version with citable page numbers, DOI, and citation export.

We apologize for the inconvenience.

Pulling the Levers of Photophysics: How Structure Controls the Rate of Energy Dissipation^†

Graphical Abstract

Supporting Information

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Pulling the Levers of Photophysics: How Structure Controls the Rate of Energy Dissipation†

Graphical Abstract

Supporting Information

References

Citing Literature

References

Related

Information

Pulling the Levers of Photophysics: How Structure Controls the Rate of Energy Dissipation^†