Zuschrift
Unusual Thermal Reactivity of [W(CPh)(NCMe)(η2-C60)(η5-C5Ph5)] in Chlorobenzene Involving Activation of All Ligands†
Dr. Wen-Yann Yeh,
Corresponding Author
Dr. Wen-Yann Yeh
Department of of Chemistry, National Sun Yat-Sen University, Kaohsiung 804 (Taiwan)
Department of of Chemistry, National Sun Yat-Sen University, Kaohsiung 804 (Taiwan)Search for more papers by this authorDr. Wen-Yann Yeh,
Corresponding Author
Dr. Wen-Yann Yeh
Department of of Chemistry, National Sun Yat-Sen University, Kaohsiung 804 (Taiwan)
Department of of Chemistry, National Sun Yat-Sen University, Kaohsiung 804 (Taiwan)Search for more papers by this author†
The author is grateful for support of this work by the National Science Council of Taiwan and thanks Mr. Ting-Shen Kuo (National Taiwan Normal University, Taipei) for X-ray diffraction analysis.
Graphical Abstract
Rummel um Wolfram: Das Erhitzen von 1 in Chlorbenzol liefert 2, 3, C6Ph6 und C60. Bei diesem Prozess werden C-H-Bindungen der Liganden aktiviert und neu gebildet, und Chloratome des Lösungsmittels werden abgespalten. C6Ph6 resultiert vermutlich aus dem Einschub des Benzylidinliganden in den C5Ph5-Ring. Im Produkt 3, einer luftstabilen 17-Elektronen-Spezies, bindet der Phenyldichlormethyl-Ligand im η3-Modus nach Art eines Allylliganden.
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