A Mixed-Solvent Strategy for Efficient Exfoliation of Inorganic Graphene Analogues†
Kai-Ge Zhou
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
Search for more papers by this authorNan-Nan Mao
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
Search for more papers by this authorHang-Xing Wang
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
Search for more papers by this authorProf. Yong Peng
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Hao-Li Zhang
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/Search for more papers by this authorKai-Ge Zhou
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
Search for more papers by this authorNan-Nan Mao
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
Search for more papers by this authorHang-Xing Wang
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
Search for more papers by this authorProf. Yong Peng
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Hao-Li Zhang
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China) http://sklaoc.lzu.edu.cn/faculty/zhanghl/Search for more papers by this authorThis work is supported by National Natural Science Foundation of China (NSFC. 21073079, J1010067), the Fundamental Research Funds for the Central Universities National Basic Research Program of China (973 Program) No.2012CB933100 and 111 Project. Helps from Mr. Xin-Hua Li in the HRTEM characterizations is also acknowledged.
Graphical Abstract
Zwei sind besser als eines: Eine auf einem Lösungsmittelgemisch basierte Methode zur Flüssigexfoliation von MoS2-, WS2- und BN-Nanoblättchen wurde entwickelt. Während EtOH und H2O jeweils schlechte Lösungsmittel für diesen Prozess sind, ergeben EtOH/H2O-Mischungen geeigneter Zusammensetzung (voraussagbar anhand der Hansen-Löslichkeitsparameter) eine effiziente Exfoliation (siehe Bild) unter Bildung hochstabiler Suspensionen.
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