Anion-Assisted Supramolecular Polymerization: From Achiral AB-Type Monomers to Chiral Assemblies†
Dr. Calogero Capici
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Search for more papers by this authorProf. Yoram Cohen
School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv (Israel)
Search for more papers by this authorDr. Alessandro D'Urso
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Dr. Giuseppe Gattuso
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorDr. Anna Notti
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Search for more papers by this authorDr. Andrea Pappalardo
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Prof. Sebastiano Pappalardo
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Prof. Melchiorre F. Parisi
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Prof. Roberto Purrello
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorDr. Sarit Slovak
School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv (Israel)
Search for more papers by this authorDr. Valentina Villari
CNR-IPCF, Istituto per i Processi Chimico-Fisici, Viale F. Stagno d'Alcontres 37, 98158 Messina (Italy)
Search for more papers by this authorDr. Calogero Capici
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Search for more papers by this authorProf. Yoram Cohen
School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv (Israel)
Search for more papers by this authorDr. Alessandro D'Urso
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Dr. Giuseppe Gattuso
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorDr. Anna Notti
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Search for more papers by this authorDr. Andrea Pappalardo
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Prof. Sebastiano Pappalardo
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Prof. Melchiorre F. Parisi
Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorCorresponding Author
Prof. Roberto Purrello
Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Giuseppe Gattuso, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Sebastiano Pappalardo, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Melchiorre F. Parisi, Dipartimento di Chimica Organica e Biologica, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)
Roberto Purrello, Dipartimento di Scienze Chimiche, Università di Catania, Viale A. Doria 6, 95125 Catania (Italy)
Search for more papers by this authorDr. Sarit Slovak
School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv (Israel)
Search for more papers by this authorDr. Valentina Villari
CNR-IPCF, Istituto per i Processi Chimico-Fisici, Viale F. Stagno d'Alcontres 37, 98158 Messina (Italy)
Search for more papers by this authorMIUR (PRIN-2009A5Y3N9 project) is gratefully acknowledged for financial support of this research.
Graphical Abstract
Anionen machen den Unterschied! Gegenionen, die während der Säure-geförderten Selbstorganisation von Monomervorstufen des AB-Typs freigesetzt werden, docken an designierte Hilfsbindungsstellen an und erleichtern somit den Poymerisierungsprozess, während sie ihre molekularen Eigenschaften auf die gesamte supramolekulare Struktur übertragen (siehe Bild).
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
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