Transformation of Methane to Propylene: A Two-Step Reaction Route Catalyzed by Modified CeO2 Nanocrystals and Zeolites†
Jieli He
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
These authors contributed equally to this work.
Search for more papers by this authorTing Xu
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
These authors contributed equally to this work.
Search for more papers by this authorZhihui Wang
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Qinghong Zhang
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorDr. Weiping Deng
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ye Wang
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorJieli He
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
These authors contributed equally to this work.
Search for more papers by this authorTing Xu
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
These authors contributed equally to this work.
Search for more papers by this authorZhihui Wang
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Qinghong Zhang
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorDr. Weiping Deng
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Ye Wang
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)
State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)Search for more papers by this authorThis work was supported by the National Basic Research Program of China (2010CB732303) and the NSF of China (21033006, 20873110, and 20923004).
Graphical Abstract
Propylen aus Methan: Eine zweistufige Route über CH3Cl oder CH3Br wandelt Methan in Propylen um. Im ersten Schritt dient CeO2 als effizienter Katalysator für die oxidative Chlorierung oder Bromierung des Methans, im zweiten Schritt wird ein modifizierter Zeolith als selektiver und stabiler Katalysator für die Umsetzung von CH3Cl oder CH3Br zu Propylen eingesetzt.
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