A Multiferroic Perdeutero Metal–Organic Framework†
Da-Wei Fu
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorCorresponding Author
Prof. Wen Zhang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. ChinaSearch for more papers by this authorDr. Hong-Ling Cai
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorDr. Yi Zhang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorDr. Jia-Zhen Ge
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorCorresponding Author
Prof. Ren-Gen Xiong
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. ChinaSearch for more papers by this authorProf. Songping D. Huang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorProf. Takayoshi Nakamura
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorDa-Wei Fu
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorCorresponding Author
Prof. Wen Zhang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. ChinaSearch for more papers by this authorDr. Hong-Ling Cai
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorDr. Yi Zhang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorDr. Jia-Zhen Ge
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorCorresponding Author
Prof. Ren-Gen Xiong
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. ChinaSearch for more papers by this authorProf. Songping D. Huang
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorProf. Takayoshi Nakamura
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, P.R. China
Search for more papers by this authorThis work was supported by the National Natural Science Foundations of China (21071030, 20931002, and 90922005) and the 973 project (2009CB6232003). X.R.G. thanks the Japanese Government for a JSPS fellowship, Joint NSFC–JSPS 21111140013 to X.R.G. and Prof. Takayoshi Nakamura (Hokkaido University) and the NSFC for a grant (20540420518) to X.R.G. and Prof. Songping D. Huang (Kent State University).
Graphical Abstract
Vitamin „D“: Das perdeuterierte Metall-organische Gerüst (MOF) [(CD3)2ND2][Co(DCOO)3] (siehe Struktur) geht zwei Phasenübergänge ein, davon einen oberhalb Raumtemperatur – ein für Metallformiate einmaliges Verhalten. Magnetische und dielektrische Hystereseschleifen machen es zu einem Beispiel für ein multiferroisches MOF ohne Kopplung der magnetischen und elektrischen Ordnung.
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