Conversion of Cobalt(II) Porphyrin into a Helical Cobalt(III) Complex of Acyclic Pentapyrrole†
Katsunori Yamanishi
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorMasamichi Miyazawa
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorTakeshi Yairi
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorShintaro Sakai
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorDr. Naoko Nishina
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorProf. Yasuhiro Kobori
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorCorresponding Author
Prof. Mitsuru Kondo
Center for Instrumental Analysis, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529 (Japan), Fax: (+81) 54-238-4763
Center for Instrumental Analysis, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529 (Japan), Fax: (+81) 54-238-4763Search for more papers by this authorKatsunori Yamanishi
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorMasamichi Miyazawa
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorTakeshi Yairi
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorShintaro Sakai
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorDr. Naoko Nishina
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorProf. Yasuhiro Kobori
Department of Chemistry, Shizuoka University (Japan)
Search for more papers by this authorCorresponding Author
Prof. Mitsuru Kondo
Center for Instrumental Analysis, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529 (Japan), Fax: (+81) 54-238-4763
Center for Instrumental Analysis, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529 (Japan), Fax: (+81) 54-238-4763Search for more papers by this authorThis work was supported by Ministry of Education, Culture, Sports, Science and Technology (Japan). M.K. thanks R. Ikeya and K. Terasaki of the Center for Instrumental Analysis in Shizuoka University for support in obtaining the X-ray diffraction data and elemental analysis data.
Graphical Abstract
Ein Bruch mit Folgen: Der CoII-Komplex eines Porphyrinliganden mit ortho-Amidophenyl-Substituent ergibt bei Einwirkung von O2 und einer koordinierenden Base einen helicalen CoIII-Komplex mit einem acyclischen Pentapyrrolliganden (siehe Bild: Co rosa, N blau, O rot, C grau). Die Enantiomere des Komplexes wurden getrennt und charakterisiert, und es wurde gezeigt, dass chirale Basen bevorzugt die (M)-helicale Form des Komplexes liefern.
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