Dinuclear Palladium(III) Complexes with a Single Unsupported Bridging Halide Ligand: Reversible Formation from Mononuclear Palladium(II) or Palladium(IV) Precursors†
Dr. Julia R. Khusnutdinova
Department of Chemistry, Washington University, St. Louis, MO 63130 (USA), Fax: (+1) 314-935-4481
Search for more papers by this authorDr. Nigam P. Rath
Department of Chemistry and Biochemistry, University of Missouri–St. Louis (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Liviu M. Mirica
Department of Chemistry, Washington University, St. Louis, MO 63130 (USA), Fax: (+1) 314-935-4481
Department of Chemistry, Washington University, St. Louis, MO 63130 (USA), Fax: (+1) 314-935-4481Search for more papers by this authorDr. Julia R. Khusnutdinova
Department of Chemistry, Washington University, St. Louis, MO 63130 (USA), Fax: (+1) 314-935-4481
Search for more papers by this authorDr. Nigam P. Rath
Department of Chemistry and Biochemistry, University of Missouri–St. Louis (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Liviu M. Mirica
Department of Chemistry, Washington University, St. Louis, MO 63130 (USA), Fax: (+1) 314-935-4481
Department of Chemistry, Washington University, St. Louis, MO 63130 (USA), Fax: (+1) 314-935-4481Search for more papers by this authorWe thank the Department of Chemistry at Washington University and American Chemical Society Petroleum Research Fund (49914-DNI3) for support. We also thank Prof. T. Daniel P. Stack for a gift of the ligand Me3tacn.
Graphical Abstract
Stabiles PdIII: Zweikernige PdIII-Komplexe des dreizähnigen Liganden Trimethyltriazacyclononan (Me3tacn) wurden durch Einelektronenoxidation einkerniger PdII-Vorstufen erhalten. Die weitere Oxidation ergab reversibel einkernige PdIV-Spezies. Die PdII- und PdIII-Komplexe spielen in der katalytischen Kharasch-Addition von Polyhalogenalkanen an Alkene eine Rolle.
Supporting Information
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