Electrically Addressable Multistate Volatile Memory with Flip-Flop and Flip-Flap-Flop Logic Circuits on a Solid Support†
Graham de Ruiter
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorLeila Motiei
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorJoyanta Choudhury
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorNoa Oded
Department of Computer Science and Applied Mathematics Weizmann Institute of Science, Rehovot (Israel)
Search for more papers by this authorMilko E. van der Boom Prof.
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorGraham de Ruiter
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorLeila Motiei
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorJoyanta Choudhury
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorNoa Oded
Department of Computer Science and Applied Mathematics Weizmann Institute of Science, Rehovot (Israel)
Search for more papers by this authorMilko E. van der Boom Prof.
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot (Israel), Fax: (+972)8-934-4142 http://www.weizmann.ac.il/oc/vanderboom/
Search for more papers by this authorThis research was supported by the Helen and Martin Kimmel Center for Molecular Design, the Yeda-Sela Center for Basic Research, and the Israel Science Foundation (ISF). J.C. thanks the FP7 program for a Marie Curie Fellowship.
Graphical Abstract
Flip-Flops: Auf der Grundlage elektrisch ansprechbarer Os2+-basierter Mehrfachschichten wurde ein mehrwertiger Arbeitsspeicher verwirklicht. Die kontrollierbaren optischen Eigenschaften der Mehrfachschichten ermöglichen den Aufbau von Speichereinheiten, die abhängig von der elektrischen Eingabe bis zu fünf verschiedene Zustände speichern können (siehe Bild). Die Speicheroperationen können durch sequenzielle, zu Flip-Flop-und Flip-Flap-Flop-Funktionseinheiten äquivalente Logikschaltkreise dargestellt werden.
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References
- 1K. Szaciłowski, Chem. Rev. 2008, 108, 3481.
- 2A. P. de Silva, H. Q. N. Gunaratne, C. P. McCoy, Nature 1993, 364, 42.
- 3
- 3aS. Silvi, E. C. Constable, C. E. Housecroft, J. E. Beves, E. L. Dunphy, M. Tamasulo, F. M. Raymo, A. Credi, Chem. Commun. 2009, 1484; S. Silvi, E. C. Constable, C. E. Housecroft, J. E. Beves, E. L. Dunphy, M. Tamasulo, F. M. Raymo, A. Credi, Chem. Eur. J. 2009, 15, 178;
- 3bS. Z. Kou, H. N. Lee, D. van Noort, K. M. K. Swamy, S. H. Kim, J. H. Soh, K. M. Lee, S. W. Nam, J. Yoon, S. Park, Angew. Chem. 2008, 120, 886; Angew. Chem. Int. Ed. 2008, 47, 872;
- 3cS. D. Straight, P. A. Liddell, Y. Terazono, T. A. Moore, A. L. Moore, D. Gust, Adv. Funct. Mater. 2007, 17, 777.
- 4
- 4aM. Semeraro, A. Credi, J. Phys. Chem. C 2010, 114, 3209;
- 4bP. Ceroni, G. Bergamini, V. Balzani, Angew. Chem. 2009, 121, 8668;
10.1002/ange.200904764 Google ScholarAngew. Chem. Int. Ed. 2009, 48, 8516;
- 4cS. Kumar, V. Luxami, R. Saini, D. Kaur, Chem. Commun. 2009, 3044;
- 4dJ. Andréasson, S. D. Straight, T. A. Moore, A. L. Moore, D. Gust, Chem. Eur. J. 2009, 15, 3936;
- 4eM. Amelia, M. Baroncini, A. Credi, Angew. Chem. 2008, 120, 6336;
10.1002/ange.200802018 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 6240;
- 4fZ. Q. Guo, W. H. Zhu, L. J. Shen, H. Tian, Angew. Chem. 2007, 119, 5645; Angew. Chem. Int. Ed. 2007, 46, 5549;
- 4gJ. Andréasson, S. D. Straight, S. Bandyopadhyay, R. H. Mitchell, T. A. Moore, A. L. Moore, D. Gust, Angew. Chem. 2007, 119, 976;
10.1002/ange.200603856 Google ScholarAngew. Chem. Int. Ed. 2007, 46, 958;
- 4hD. Margulies, G. Melman, A. Shanzer, Nat. Mater. 2005, 4, 768.
- 5
- 5aG. de Ruiter, E. Tartakovsky, N. Oded, M. E. van der Boom, Angew. Chem. 2010, 122, 173;
10.1002/ange.200905358 Google ScholarAngew. Chem. Int. Ed. 2010, 49, 169;
- 5bU. Pischel, Angew. Chem. 2010, 122, 1396;
10.1002/ange.200906705 Google ScholarAngew. Chem. Int. Ed. 2010, 49, 1356;
- 5cJ. Kärnbratt, M. Hammarson, S. Li, L. Anderson, B. Albinsson, J. Andreasson, Angew. Chem. 2010, 122, 1898;
10.1002/ange.200906088 Google ScholarAngew. Chem. Int. Ed. 2010, 49, 1854;
- 5dG. Periyasamy, J. P. Collin, J. P. Sauvage, R. D. Levine, F. Remacle, Chem. Eur. J. 2009, 15, 1310;
- 5eR. Baron, A. Onopriyenko, E. Katz, O. Lioubashevski, I. Willner, W. Sheng, H. Tian, Chem. Commun. 2006, 2147.
- 6
- 6aT. Tarkeshwar, E. Tartakovsky, M. A. Iron, M. E. van der Boom, ACS Appl. Mater. Interfaces 2010, 2, 7;
- 6bT. Gupta, M. E. van der Boom, Angew. Chem. 2008, 120, 5402; Angew. Chem. Int. Ed. 2008, 47, 5322;
- 6c T. Gupta, M. E. van der Boom, Angew. Chem. 2008, 120, 2292; Angew. Chem. Int. Ed. 2008, 47, 2260;
- 6dA. N. Shipway, E. Katz, I. Willner, Molecular Memory and Processing Devices in Solution and on Surfaces. Vol. 99, Springer, Berlin, 2001, p. 237.
- 7For recent reviews see:
- 7aJ. Andréasson, U. Pischel, Chem. Soc. Rev. 2010, 39, 174;
- 7bA. P. de Silva, S. Uchiyama, Nat. Nanotechnol. 2007, 2, 399;
- 7cA. Credi, Angew. Chem. 2007, 119, 5568;
10.1002/ange.200700879 Google ScholarAngew. Chem. Int. Ed. 2007, 46, 5472;
- 7dU. Pischel, Angew. Chem. 2007, 119, 4100;
10.1002/ange.200603990 Google ScholarAngew. Chem. Int. Ed. 2007, 46, 4026.
- 8
- 8aG. Zong, G. Lu, J. Phys. Chem. C 2009, 113, 2541;
- 8bM. Suresh, A. Ghosh, A. Das, Chem. Commun. 2008, 3906;
- 8cS. Alves, F. Pina, M. T. Albeda, E. Garcia-Espana, C. Soriano, S. V. Luis, Eur. J. Inorg. Chem. 2001, 405.
- 9T. Konry, D. R. Walt, J. Am. Chem. Soc. 2009, 131, 13232.
- 10A. Prasanna de Silva, M. R. James, B. O. F. McKinney, D. A. Pears, S. M. Weir, Nat. Mater. 2006, 5, 787.
- 11
- 11aG. Boole, An Investigation of the laws of thought, Dover, New York, 1849 (1954 Reprint);
- 11bG. Boole, The Mathematical Analysis of Logic. Blackwell, Oxford, 1948 (reprint).
- 12
- 12aS. L. Hurst, IEEE Trans. Comput. 1984, c-33, 1160;
- 12bB. Hayes, Am. Sci. 2001, 89, 490.
- 13The increased information density is obtained from ln(3)/ln(2).[14]
- 14D. E. Knuth, The Art of Computer Programming; Numerical Algorithms. 3rd ed., Addison-Wesley, Reading, MA, 1997.
- 15
- 15aR. Ferreira, P. Remon, P. U. Pischel, J. Phys. Chem. C 2009, 113, 5805;
- 15bM. Klein, S. R. Rogge, F. Remacle, R. D. Levine, Nano Lett. 2007, 7, 2795.
- 16For a molecular binary DRAM see; J. E. Green, et al., Nature 2007, 445, 414; or for an electrically addressable flip-flop, see Ref. [5d].
- 17M. M. Mano, C. R. Kime, Logic and Computer Design Fundamentals, 4th ed., Prentice Hall, Upper Saddle River, NJ, 2000.
- 18
- 18aA. Stakhov, The Computer Journal 2002, 45, 221;
- 18bT. A. Irving, S. G. Shiva, H. T. Nagle, IEEE Trans. Comput. 1976, c-25, 237.
- 19
- 19aL. Motiei, M. Lahav, D. Freeman, M. E. van der Boom, J. Am. Chem. Soc. 2009, 131, 3468;
- 19bL. Motiei, M. Altman, T. Gupta, F. Lupo, A. Gulino, G. Evmenenko, P. Dutta, M. E. van der Boom, J. Am. Chem. Soc. 2008, 130, 8913.
- 20T. Gupta, M. E. van der Boom, J. Am. Chem. Soc. 2006, 128, 8400.
- 21G. Periyasamy, R. D. Levine, F. Remacle, Aust. J. Chem. 2010, 63, 173.
- 22J. Lee, H. Chang, S. Kim, G. S. Bang, H, Lee, Angew. Chem. 2009, 121, 8653; Angew. Chem. Int. Ed. 2009, 48, 8501.
- 23I. F. Perepichka, D. F. Perepichka, D. F. Handbook of Thiophene-Based Materials; Applications in Organic Electronics and Photonics, John Wiley & Sons, Chichester, 2009.
10.1002/9780470745533 Google Scholar
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