Covalent Layer-by-Layer Assembly and Solvent Memory of Multilayer Films from Homobifunctional Poly(dimethylsiloxane)†
Rohama Gill Dr.
Present address: Department of Environmental Sciences, Fatima Jinnah Women University (Pakistan)
C.N.R.S. Institut Charles Sadron, 23, rue du Loess, 67034 Strasbourg (France), Fax: (+33) 3-8841-4099
Department Of Chemistry, Quaid-i-Azam University, Islamabad-45320 (Pakistan)
Search for more papers by this authorMuhammad Mazhar Prof.
Present address: Department of Chemistry, University of Malaya (Malaysia)
Department Of Chemistry, Quaid-i-Azam University, Islamabad-45320 (Pakistan)
Search for more papers by this authorOlivier Félix Dr.
C.N.R.S. Institut Charles Sadron, 23, rue du Loess, 67034 Strasbourg (France), Fax: (+33) 3-8841-4099
Search for more papers by this authorGero Decher Prof. Dr.
C.N.R.S. Institut Charles Sadron, 23, rue du Loess, 67034 Strasbourg (France), Fax: (+33) 3-8841-4099
Faculté de Chimie, Université de Strasbourg, 1, rue Blaise Pascal, 67008 Strasbourg (France)
International Center for Frontier Research in Chemistry, 8, allée Gaspard Monge, 6700 Strasbourg (France)
Search for more papers by this authorRohama Gill Dr.
Present address: Department of Environmental Sciences, Fatima Jinnah Women University (Pakistan)
C.N.R.S. Institut Charles Sadron, 23, rue du Loess, 67034 Strasbourg (France), Fax: (+33) 3-8841-4099
Department Of Chemistry, Quaid-i-Azam University, Islamabad-45320 (Pakistan)
Search for more papers by this authorMuhammad Mazhar Prof.
Present address: Department of Chemistry, University of Malaya (Malaysia)
Department Of Chemistry, Quaid-i-Azam University, Islamabad-45320 (Pakistan)
Search for more papers by this authorOlivier Félix Dr.
C.N.R.S. Institut Charles Sadron, 23, rue du Loess, 67034 Strasbourg (France), Fax: (+33) 3-8841-4099
Search for more papers by this authorGero Decher Prof. Dr.
C.N.R.S. Institut Charles Sadron, 23, rue du Loess, 67034 Strasbourg (France), Fax: (+33) 3-8841-4099
Faculté de Chimie, Université de Strasbourg, 1, rue Blaise Pascal, 67008 Strasbourg (France)
International Center for Frontier Research in Chemistry, 8, allée Gaspard Monge, 6700 Strasbourg (France)
Search for more papers by this authorWe gratefully acknowledge support from the International Research Support Initiative of the Higher Education Commission of Pakistan and from the CNRS. We thank Christophe Contal for invaluable help with the AFM measurements. G.D. thanks the Institut Universitaire de France for support.
Graphical Abstract
Mit einer einfachen Prozedur gelingt der kovalente schichtweise Aufbau (Layer-by-Layer, LbL) von homodifunktionellem H2N-Poly(dimethoxysilan)-NH2 auf SiO2-Oberflächen. Man erhält robuste LbL-Filme von optischer Qualität (siehe Bild, Photo links) trotz Verwendung nicht gereinigter kommerzieller Ausgangsmaterialien. Die Filme zeigen ein Solvensgedächtnis bezüglich ihres Quellverhaltens in den Lösungsmitteln der entsprechenden Polymere.
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