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A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters^†

Shu-Dan Bian

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 (P. R. China), Fax: (+86) 592-218-3047

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Hua-Bin Wu,

Hua-Bin Wu

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 (P. R. China), Fax: (+86) 592-218-3047

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Quan-Ming Wang Prof. Dr.,

Quan-Ming Wang Prof. Dr.

[email protected]

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 (P. R. China), Fax: (+86) 592-218-3047

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Shu-Dan Bian,

Shu-Dan Bian

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 (P. R. China), Fax: (+86) 592-218-3047

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Hua-Bin Wu,

Hua-Bin Wu

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 (P. R. China), Fax: (+86) 592-218-3047

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Quan-Ming Wang Prof. Dr.,

Quan-Ming Wang Prof. Dr.

[email protected]

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005 (P. R. China), Fax: (+86) 592-218-3047

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First published: 01 July 2009

https://doi.org/10.1002/ange.200902279

Citations: 36

^†

This work was supported by the Natural Science Foundation of China (20771091 and 20721001), the 973 Program (2007CB815301), and the Ministry of Education (NCET-06-0563).

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Abstract

Erdnussförmig: Eine einfache Synthese großer Silbercluster nutzt Anionen als Template. Die Zahl an Silberatomen im Cluster lässt sich über die Größe des Templats und die Eigenschaften der Alkinylliganden einstellen. Für den größten Cluster mit 35 Silber(I)-Zentren wurden Chromat-Ionen als Templat eingesetzt (siehe Bild).

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References

1A. Müller, Science 2003, 300, 749–750.
10.1126/science.1084991
CAS PubMed Web of Science® Google Scholar
2R. E. P. Winpenny, J. Chem. Soc. Dalton Trans. 2002, 1–10.
10.1039/b107118c
CAS Web of Science® Google Scholar
3C. E. Anson, A. Eichhöfer, I. Issac, D. Fenske, O. Fuhr, P. Sevillano, C. Persau, D. Stalke, J.-T. Zhang, Angew. Chem. 2008, 120, 1346–1351;
10.1002/ange.200704249
Google Scholar
Angew. Chem. Int. Ed. 2008, 47, 1326–1331.
10.1002/anie.200704249
CAS PubMed Web of Science® Google Scholar
4X.-J. Kong, Y.-P. Ren, L.-S. Long, Z.-P. Zheng, R.-B. Huang, L.-S. Zheng, J. Am. Chem. Soc. 2007, 129, 7016–7017.
10.1021/ja0726198
CAS PubMed Web of Science® Google Scholar
5S. Anderson, H. L. Anderson, J. K. M. Sanders, Acc. Chem. Res. 1993, 26, 469.
10.1021/ar00033a003
CAS Web of Science® Google Scholar
6P. D. Beer, P. A. Gale, Angew. Chem. 2001, 113, 502–532;
10.1002/1521-3757(20010202)113:3<502::AID-ANGE502>3.0.CO;2-A
Google Scholar
Angew. Chem. Int. Ed. 2001, 40, 486–516;
10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO;2-P
CAS PubMed Web of Science® Google Scholar
P. A. Gale, Coord. Chem. Rev. 2000, 199, 181;
10.1016/S0010-8545(99)00149-6
CAS Web of Science® Google Scholar
P. A. Gale, Coord. Chem. Rev. 2001, 213, 79.
10.1016/S0010-8545(00)00364-7
CAS Web of Science® Google Scholar
7R. Vilar, Angew. Chem. 2003, 115, 1498–1516;
10.1002/ange.200200551
Web of Science® Google Scholar
Angew. Chem. Int. Ed. 2003, 42, 1460–1477;
10.1002/anie.200200551
CAS PubMed Web of Science® Google Scholar
R. Vilar, Eur. J. Inorg. Chem. 2008, 357.
10.1002/ejic.200701017
CAS Web of Science® Google Scholar
8D. M. P. Mingos, R. Vilar, D. Rais, J. Organomet. Chem. 2002, 641, 126–133.
10.1016/S0022-328X(01)01305-5
CAS Web of Science® Google Scholar
9T. C. W. Mak, L. Zhao, Chem. Asian J. 2007, 2, 456–467.
10.1002/asia.200600386
CAS PubMed Web of Science® Google Scholar
10D. Rais, J. Yau, D. M. P. Mingos, R. Vilar, A. J. P. White, D. J. Williams, Angew. Chem. 2001, 113, 3572–3575;
10.1002/1521-3757(20010917)113:18<3572::AID-ANGE3572>3.0.CO;2-M
Google Scholar
Angew. Chem. Int. Ed. 2001, 40, 3464–3467.
10.1002/1521-3773(20010917)40:18<3464::AID-ANIE3464>3.0.CO;2-M
CAS PubMed Web of Science® Google Scholar
11S.-D. Bian, J.-H. Jia, Q.-M. Wang, J. Am. Chem. Soc. 2009, 131, 3422–3423.
10.1021/ja8087696
CAS PubMed Web of Science® Google Scholar
12Crystal data for 1: [C₁₀₈H₁₆₂B₂O₄F₈CrAg₂₂], monoclinic, P2₁/n, a=21.8762(5), b=21.6612(6), c=28.2026(8) Å, β=91.033(2), V=13 362.0(6) Å³, Z=4, T=173 K, 77 080 reflections measured, 35 799 unique (R_int=0.148), final R1=0.0529, wR2=0.0723 for 8235 observed reflections [I>2σ(I)]. Crystal data for 2, [C₁₀₈H₁₆₂B O₄F₄SAg₂₁], monoclinic, Pn, a=15.3810(3), b=15.7752(4), c=27.3409(5) Å, β=94.834(2), V=6610.4(2) Å³, Z=2, T=173 K, 47 221 reflections measured, 27 050 unique (R_int=0.0548), final R1=0.0438, wR2=0.0708 for 11 807 observed reflections [I>2σ(I)]. Crystal data for 3, [C₂₄₈H₂₀₄B₃N₈O₈F₁₂Cr₂Ag₃₅], monoclinic, P2₁/c, a=37.3001(9), b=19.6190(3), c=36.5984(7) Å, β=112.173(3), V=24 801.8(9) Å³, Z=4, T=173 K, 101 441 reflections measured, 38 002 unique (R_int=0.1424), final R1=0.0760, wR2=0.1607 for 14 639 observed reflections [I>2σ(I)]. CCDC 729707 (1), CCDC 729708 (2) and CCDC 729709 (3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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Volume121, Issue29

July 6, 2009

Pages 5467-5469

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A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters^†

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A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters†

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A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters^†