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A Reactive Niobium Phosphinidene P₈ Cluster Obtained by Reductive Coupling of White Phosphorus^†

Brandi M. Cossairt

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA, Fax: (+1)-617-258-5700

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Christopher C. Cummins Prof. Dr.,

Christopher C. Cummins Prof. Dr.

[email protected]

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA, Fax: (+1)-617-258-5700

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Brandi M. Cossairt,

Brandi M. Cossairt

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA, Fax: (+1)-617-258-5700

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Christopher C. Cummins Prof. Dr.,

Christopher C. Cummins Prof. Dr.

[email protected]

Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA, Fax: (+1)-617-258-5700

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First published: 13 December 2007

https://doi.org/10.1002/ange.200704354

Citations: 22

^†

We gratefully acknowledge the US National Science Foundation grant CHE-719157, Thermphos International, and the Massachusetts Institute of Technology for funding.

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Graphical Abstract

4 + 4 = 8: Die Disproportionierung von [NbI(OC[²Ad]Mes)₃(thf)] in Gegenwart von weißem Phosphor (P₄) resultiert in der reduktiven Kupplung zweier P₄-Moleküle. Der entstehende Dimetallkomplex enthält eine reaktive Niobphosphiniden-Einheit; ein einkerniges Hydrolyseprodukt konnte strukturanalytisch charakterisiert werden (siehe Bild: P orange, Nb violett, O rot). ²Ad = 2-Adamantyliden, Mes = 2,4,6-Me₃C₆H₂.

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Volume120, Issue1

December 17, 2007

Pages 175-178

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A Reactive Niobium Phosphinidene P₈ Cluster Obtained by Reductive Coupling of White Phosphorus^†

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A Reactive Niobium Phosphinidene P8 Cluster Obtained by Reductive Coupling of White Phosphorus†

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A Reactive Niobium Phosphinidene P₈ Cluster Obtained by Reductive Coupling of White Phosphorus^†