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Thin, Conformal, and Continuous SnO₂ Coatings on Three-Dimensional Biosilica Templates through Hydroxy-Group Amplification and Layer-By-Layer Alkoxide Deposition^†

Michael R. Weatherspoon

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Matthew B. Dickerson,

Matthew B. Dickerson

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Guojie Wang Dr.,

Guojie Wang Dr.

School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332-0400, USA, Fax: (+1) 404-894-5909

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Ye Cai Dr.,

Ye Cai Dr.

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Samuel Shian,

Samuel Shian

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Simon C. Jones Dr.,

Simon C. Jones Dr.

School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332-0400, USA, Fax: (+1) 404-894-5909

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Seth R. Marder Prof. Dr.,

Seth R. Marder Prof. Dr.

[email protected]

School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332-0400, USA, Fax: (+1) 404-894-5909

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Kenneth H. Sandhage Prof. Dr.,

Kenneth H. Sandhage Prof. Dr.

[email protected]

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Michael R. Weatherspoon,

Michael R. Weatherspoon

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Matthew B. Dickerson,

Matthew B. Dickerson

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Guojie Wang Dr.,

Guojie Wang Dr.

School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332-0400, USA, Fax: (+1) 404-894-5909

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Ye Cai Dr.,

Ye Cai Dr.

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Samuel Shian,

Samuel Shian

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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Simon C. Jones Dr.,

Simon C. Jones Dr.

School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332-0400, USA, Fax: (+1) 404-894-5909

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Seth R. Marder Prof. Dr.,

Seth R. Marder Prof. Dr.

[email protected]

School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive, Atlanta, GA 30332-0400, USA, Fax: (+1) 404-894-5909

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Kenneth H. Sandhage Prof. Dr.,

Kenneth H. Sandhage Prof. Dr.

[email protected]

School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA 30332-0245, USA, Fax: (+1) 404-385-6564 http://www.gems.gatech.edu

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First published: 13 July 2007

https://doi.org/10.1002/ange.200701297

Citations: 21

^†

This work was supported by the Office of Naval Research (Dr. Mark Spector, Program Manager) and the Air Force Office of Scientific Research (Dr. Joan Fuller, Dr. Hugh DeLong, Program Managers). The authors acknowledge the Georgia Tech FIB² Center established under NSF funding.

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Graphical Abstract

Biogerüst funktionalisiert: Ein Verfahren wird vorgestellt, um feine Biokieselsäurestrukturen mit funktionellen Oxiden zu belegen. Durch dendritische Amplifikation von Oberflächen-Hydroxygruppen und anschließende Sol-Gel-Behandlung lassen sich dünne Schichten von SnO₂ auf die Kieselsäure-Valven von Diatomeen aufbringen (siehe Bild). Die SnO₂-bedeckten Valven fungieren als empfindliche Detektoren für NO-Gas.

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Volume119, Issue30

July 23, 2007

Pages 5826-5829

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Thin, Conformal, and Continuous SnO₂ Coatings on Three-Dimensional Biosilica Templates through Hydroxy-Group Amplification and Layer-By-Layer Alkoxide Deposition^†

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Thin, Conformal, and Continuous SnO2 Coatings on Three-Dimensional Biosilica Templates through Hydroxy-Group Amplification and Layer-By-Layer Alkoxide Deposition†

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Thin, Conformal, and Continuous SnO₂ Coatings on Three-Dimensional Biosilica Templates through Hydroxy-Group Amplification and Layer-By-Layer Alkoxide Deposition^†