Electric-Field Modulation of Component Exchange in Constitutional Dynamic Liquid Crystals†
Nicolas Giuseppone Dr.
Institut de Science et d'Ingénierie Supramoléculaires, 8 Allée Gaspard-Monge, BP 70028, 67083 Strasbourg, France, Fax: (+33) 390-245-140
Search for more papers by this authorJean-Marie Lehn Prof. Dr.
Institut de Science et d'Ingénierie Supramoléculaires, 8 Allée Gaspard-Monge, BP 70028, 67083 Strasbourg, France, Fax: (+33) 390-245-140
Search for more papers by this authorNicolas Giuseppone Dr.
Institut de Science et d'Ingénierie Supramoléculaires, 8 Allée Gaspard-Monge, BP 70028, 67083 Strasbourg, France, Fax: (+33) 390-245-140
Search for more papers by this authorJean-Marie Lehn Prof. Dr.
Institut de Science et d'Ingénierie Supramoléculaires, 8 Allée Gaspard-Monge, BP 70028, 67083 Strasbourg, France, Fax: (+33) 390-245-140
Search for more papers by this authorWe thank Dr. Jean-Louis Schmitt for checking the experimental results. We are grateful to Dr. Daniel Guillon, Dr. Jacques Malthête, and Dr. Jacques Prost for their constructive remarks on the manuscript.
Graphical Abstract
Feldspiele: Ein elektrisches Feld beeinflusst die thermodynamischen Gleichgewichte von konstitutionell dynamischen Sätzen aus Iminen und Aminen mit einem Imin, das flüssigkristalline Eigenschaften und eine negative dielektrische Anisotropie hat, in einer Weise, dass derjenige Bestandteil amplifiziert wird, der am stärksten mit dem elektrischen Feld koppelt: der Flüssigkristall (LC). Das Feld kann somit einen Übergang zwischen flüssiger und nematischer Phase induzieren.
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