Lattice Expansion of Clathrate Hydrates of Methane Mixtures and Natural Gas†
Satoshi Takeya Dr.
Research Institute of Instrumentation Frontier (RIIF), National Institute of Advanced Industrial Science and Technology (AIST), Central 5, Higashi 1-1-1, Tsukuba 305-8565, Japan, Fax: (+81) 29-861-4506
Search for more papers by this authorTsutomu Uchida Dr.
Department of Applied Physics, Hokkaido University, N13W8 Sapporo 060-8628, Japan
Search for more papers by this authorYasushi Kamata Dr.
Methane Hydrate Research Laboratory, AIST, 2-17 Tukisamu Higashi Toyohira-ku, Sapporo 062-8517, Japan
Search for more papers by this authorJiro Nagao Dr.
Methane Hydrate Research Laboratory, AIST, 2-17 Tukisamu Higashi Toyohira-ku, Sapporo 062-8517, Japan
Search for more papers by this authorMasato Kida
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorHirotsugu Minami Dr.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorHirotoshi Sakagami Dr.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorAkihiro Hachikubo Dr.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorNobuo Takahashi Prof.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorHitoshi Shoji Prof.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorOleg Khlystov Dr.
Russian Academy of Sciences Siberian Branch Limnological Institute, 3 Ulan-Batorskaya, Irkutsk 664033, Russia
Search for more papers by this authorMikhail Grachev Dr.
Russian Academy of Sciences Siberian Branch Limnological Institute, 3 Ulan-Batorskaya, Irkutsk 664033, Russia
Search for more papers by this authorValery Soloviev Dr.
All-Russia Research Institute for Geology and Mineral Resources of the Ocean, Saint Petersburg 190121, Russia
Search for more papers by this authorSatoshi Takeya Dr.
Research Institute of Instrumentation Frontier (RIIF), National Institute of Advanced Industrial Science and Technology (AIST), Central 5, Higashi 1-1-1, Tsukuba 305-8565, Japan, Fax: (+81) 29-861-4506
Search for more papers by this authorTsutomu Uchida Dr.
Department of Applied Physics, Hokkaido University, N13W8 Sapporo 060-8628, Japan
Search for more papers by this authorYasushi Kamata Dr.
Methane Hydrate Research Laboratory, AIST, 2-17 Tukisamu Higashi Toyohira-ku, Sapporo 062-8517, Japan
Search for more papers by this authorJiro Nagao Dr.
Methane Hydrate Research Laboratory, AIST, 2-17 Tukisamu Higashi Toyohira-ku, Sapporo 062-8517, Japan
Search for more papers by this authorMasato Kida
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorHirotsugu Minami Dr.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorHirotoshi Sakagami Dr.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorAkihiro Hachikubo Dr.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorNobuo Takahashi Prof.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorHitoshi Shoji Prof.
Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Fax: (+81) 157-26-9534
Search for more papers by this authorOleg Khlystov Dr.
Russian Academy of Sciences Siberian Branch Limnological Institute, 3 Ulan-Batorskaya, Irkutsk 664033, Russia
Search for more papers by this authorMikhail Grachev Dr.
Russian Academy of Sciences Siberian Branch Limnological Institute, 3 Ulan-Batorskaya, Irkutsk 664033, Russia
Search for more papers by this authorValery Soloviev Dr.
All-Russia Research Institute for Geology and Mineral Resources of the Ocean, Saint Petersburg 190121, Russia
Search for more papers by this authorS.T. thanks H. Fujihisa, Y. Gotoh, and K. Honda of AIST for their valuable comments and discussions, and H. Narita of AIST for his support in experiments.
Graphical Abstract
Der I→II-Strukturübergang von (CH4+C2H6)-Clathrathydraten geht mit einer starken Vergrößerung der Gitterkonstanten a einher (siehe Bild), wohingegen die Gitterkonstanten von (CH4+CO2)-Clathrathydraten von der Zusammensetzung unabhängig sind. Untersuchungen natürlicher Gashydrate aus Sedimenten des Baikal-Sees bestätigen dieses Verhalten.
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