Volume 117, Issue 19 pp. 2976-2978

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Synthesis and Characterization of [exo-BH₂(CpM)₂B₉H₁₄] (M=Ru, Re), and the Conversion of the Ruthenaborane into [(CpRu)₂B₁₀H₁₆] with an Open Cluster Framework Based on a Capped Truncated Tetrahedron^†

Sundargopal Ghosh,

Sundargopal Ghosh

Department of Chemistry, University of Notre Dame, Notre Dame, IN 46556, USA, Fax: (+1) 504-631-7234

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Bruce C. Noll,

Bruce C. Noll

Department of Chemistry, University of Notre Dame, Notre Dame, IN 46556, USA, Fax: (+1) 504-631-7234

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Thomas P. Fehlner Prof.,

Thomas P. Fehlner Prof.

[email protected]

Department of Chemistry, University of Notre Dame, Notre Dame, IN 46556, USA, Fax: (+1) 504-631-7234

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Sundargopal Ghosh,

Sundargopal Ghosh

Department of Chemistry, University of Notre Dame, Notre Dame, IN 46556, USA, Fax: (+1) 504-631-7234

Search for more papers by this author

Bruce C. Noll,

Bruce C. Noll

Department of Chemistry, University of Notre Dame, Notre Dame, IN 46556, USA, Fax: (+1) 504-631-7234

Search for more papers by this author

Thomas P. Fehlner Prof.,

Thomas P. Fehlner Prof.

[email protected]

Department of Chemistry, University of Notre Dame, Notre Dame, IN 46556, USA, Fax: (+1) 504-631-7234

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First published: 03 May 2005

https://doi.org/10.1002/ange.200500343

Citations: 8

^†

This work was supported by the National Science Foundation (CHE-0304008); Cp*=η⁵-C₅Me₅.

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Graphical Abstract

Bor wird in die Ecke getrieben: Beim Erhitzen inseriert die exo-BH₂-Brücke auf einem {(Cp*Ru)₂B₉H₁₄}-Gerüst (1; Cp*=C₅Me₅) in das Clustergerüst, wobei ein Produkt mit zwölf Ecken und offenem Gerüst entsteht: [(Cp*Ru)₂B₁₀H₁₆] (2).

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Volume117, Issue19

May 6, 2005

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Synthesis and Characterization of [exo-BH₂(CpM)₂B₉H₁₄] (M=Ru, Re), and the Conversion of the Ruthenaborane into [(CpRu)₂B₁₀H₁₆] with an Open Cluster Framework Based on a Capped Truncated Tetrahedron^†

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Synthesis and Characterization of [exo-BH2(Cp*M)2B9H14] (M=Ru, Re), and the Conversion of the Ruthenaborane into [(Cp*Ru)2B10H16] with an Open Cluster Framework Based on a Capped Truncated Tetrahedron†

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Synthesis and Characterization of [exo-BH₂(CpM)₂B₉H₁₄] (M=Ru, Re), and the Conversion of the Ruthenaborane into [(CpRu)₂B₁₀H₁₆] with an Open Cluster Framework Based on a Capped Truncated Tetrahedron^†