Zuschrift

High-Resolution NMR Spectroscopy in Solids by Truly Magic-Angle Spinning^†

Sasa Antonijevic Dr.

Laboratoire de Résonance Magnétique Biomoléculaire (LRMB), Institut des Sciences et Ingénierie Chimiques (ISIC), Ecole Polytechnique Fédérale de Lausanne (EPFL), BCH, 1015 Lausanne, Switzerland, Fax: (+41) 21-693-9435

Search for more papers by this author

Geoffrey Bodenhausen Prof. Dr.,

Geoffrey Bodenhausen Prof. Dr.

[email protected]

Département de Chimie associé au CNRS, Ecole Normale Supérieure, 24 rue Lhomond 75231, Paris Cedex 05, France

Search for more papers by this author

Sasa Antonijevic Dr.,

Sasa Antonijevic Dr.

Search for more papers by this author

Geoffrey Bodenhausen Prof. Dr.,

Geoffrey Bodenhausen Prof. Dr.

[email protected]

Département de Chimie associé au CNRS, Ecole Normale Supérieure, 24 rue Lhomond 75231, Paris Cedex 05, France

Search for more papers by this author

First published: 03 May 2005

https://doi.org/10.1002/ange.200463049

Citations: 5

^†

This work was supported by the Fonds National de la Recherche Scientifique (FNRS) and the Commission pour la Technologie et l'Innovation (CTI), Switzerland.

Share a link

Email
Wechat
Bluesky

Graphical Abstract

Der rechte Winkel: In Festkörper-MAS-NMR-Spektren sind die Signalbreiten von Carbonyl-Kohlenstoffatomen in polykristallinem Cholesterylacetat nicht breiter als 0.039 ppm, wenn der magische Winkel sehr genau eingestellt wird, d. h. auf ±0.004° (siehe Bild). Die bei geringer Abweichung vom Idealwert beobachtete Signalverbreiterung ist vor allem auf Restwechselwirkungen aufgrund der chemischen Verschiebungsanisotropie zurückzuführen. Lange Spinecho-Lebensdauern bis equation image =3.6 s eröffnen den Weg für fortgeschrittene Methoden.

References

1F. Castellani, B. van Rossum, A. Diehl, M. Schubert, K. Rehbein, H. Oschkinat, Nature 2002, 420, 98.
10.1038/nature01070
CAS PubMed Web of Science® Google Scholar
2M. Etzkorn, A. Böckmann, A. Lange, M. Baldus, J. Am. Chem. Soc. 2004, 126, 14 746.
10.1021/ja0479181
CAS Web of Science® Google Scholar
3M. Ernst, A. Detken, A. Bockmann, B. H. Meier, J. Am. Chem. Soc. 2003, 125, 15 807.
10.1021/ja0369966
CAS Web of Science® Google Scholar
4P. A. Tishmack, D. E. Bugay, S. R. Byrn, J. Pharm. Sci. 2003, 92, 441.
10.1002/jps.10307
CAS PubMed Web of Science® Google Scholar
5Z. Gan, J. Am. Chem. Soc. 2000, 122, 3242.
10.1021/ja9939791
CAS Web of Science® Google Scholar
6S. E. Ashbrook, S. Wimperis, J. Magn. Reson. 2002, 156, 269.
10.1006/jmre.2002.2557
CAS PubMed Web of Science® Google Scholar
7G. De Paëpe, A. Lesage, L. Emsley, J. Chem. Phys. 2003, 119, 4833.
10.1063/1.1595088
CAS Web of Science® Google Scholar
8D. Sakellariou, S. P. Brown, A. Lesage, S. Hediger, M. Bardet, C. A. Meriles, A. Pines, L. Emsley, J. Am. Chem. Soc. 2003, 125, 4376.
10.1021/ja0292389
CAS PubMed Web of Science® Google Scholar
9M. Alla, E. Lippmaa, Chem. Phys. Lett. 1982, 87, 30.
10.1016/0009-2614(82)83547-1
CAS Web of Science® Google Scholar
10A. Samoson, T. Tuherm, Z. Gan, Solid State Nucl. Magn. Reson. 2001, 20, 130.
10.1006/snmr.2001.0037
CAS PubMed Web of Science® Google Scholar
11S. E. Ashbrook, S. Antonijevic, A. J. Berry, S. Wimperis, Chem. Phys. Lett. 2002, 364, 634.
10.1016/S0009-2614(02)01412-4
CAS Web of Science® Google Scholar
12G. De Paëpe, A. Lesage, S. Steuernagel, L. Emsley, ChemPhysChem 2004, 5, 869.
10.1002/cphc.200301062
CAS PubMed Web of Science® Google Scholar
13C. Ye, R. Fu, J. Hu, L. Hou, S. Ding, Magn. Reson. Chem. 1993, 31, 699.
10.1002/mrc.1260310802
CAS Web of Science® Google Scholar
14J. G. Hexem, M. H. Frey, S. J. Opella, J. Am. Chem. Soc. 1981, 103, 224.
10.1021/ja00391a057
CAS Web of Science® Google Scholar
15A. Naito, S. Ganapathy, C. A. McDowell, J. Chem. Phys. 1981, 74, 5393.
10.1063/1.440968
CAS Web of Science® Google Scholar
16K. Takegoshi, T. Yano, K. Takeda, T. Terao, J. Am. Chem. Soc. 2001, 123, 10 786.
10.1021/ja016789a
CAS Web of Science® Google Scholar
17R. K. Harris, A. C. Olivieri, Prog. Nucl. Magn. Reson. Spectrosc. 1992, 24, 435.
10.1016/0079-6565(92)80004-Y
CAS Web of Science® Google Scholar
18C. A. McDowell in Encyclopedia of Nuclear Magnetic Resonance, Vol. 5 (Ed.: ), Wiley, Chichester, 1996, p. 2901.
Google Scholar
19G. De Paëpe, N. Giraud, A. Lesage, P. Hodgkinson, A. Böckmann, L. Emsley, J. Am. Chem. Soc. 2003, 125, 13 938.
10.1021/ja037213j
Web of Science® Google Scholar
20A. Medek, L. Frydman, J. Am. Chem. Soc. 2000, 122, 684.
10.1021/ja992939u
CAS Web of Science® Google Scholar
21F. Aguilar-Parrilla, B. Wehrle, H. Braunling, H. H. Limbach, J. Magn. Reson. 1990, 87, 592.
10.1016/0022-2364(90)90315-Z
CAS Web of Science® Google Scholar
22L. C. M. van Gorkom, J. M. Hook, M. B. Logan, J. V. Hanna, R. E. Wasylishen, Magn. Reson. Chem. 1995, 33, 791.
10.1002/mrc.1260331005
CAS Web of Science® Google Scholar
23B. Langer, I. Schnell, H. W. Spiess, A.-R. Grimmer, J. Magn. Reson. 1999, 138, 182.
10.1006/jmre.1999.1717
CAS PubMed Web of Science® Google Scholar
24P. A. Beckmann, C. Dybowski, J. Magn. Reson. 2000, 146, 379.
10.1006/jmre.2000.2171
CAS PubMed Web of Science® Google Scholar
25A. L. van Geet, Anal. Chem. 1970, 42, 679.
10.1021/ac60288a022
CAS Web of Science® Google Scholar

Citing Literature

Volume117, Issue19

May 6, 2005

Pages 2995-2998

This is the

German version

of Angewandte Chemie.

Note for articles published since 1962:

Do not cite this version alone.

Take me to the International Edition version with citable page numbers, DOI, and citation export.

We apologize for the inconvenience.

High-Resolution NMR Spectroscopy in Solids by Truly Magic-Angle Spinning^†

Graphical Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

High-Resolution NMR Spectroscopy in Solids by Truly Magic-Angle Spinning†

Graphical Abstract

References

Citing Literature

References

Related

Information

High-Resolution NMR Spectroscopy in Solids by Truly Magic-Angle Spinning^†