A Dramatic Push Effect on the Homolysis of FeIII(OOR) Intermediates To Form Non-Heme FeIVO Complexes†
József Kaizer Dr.
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorMiquel Costas Dr.
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorLawrence Que Jr. Prof.
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorJózsef Kaizer Dr.
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorMiquel Costas Dr.
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorLawrence Que Jr. Prof.
Department of Chemistry and Center for Metals In Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorWe thank A. Stubna and Professor E. Münck for obtaining the Mössbauer data for complex 2. This work was supported by a grant (GM33162) from the US National Institutes of Health.
Graphical Abstract
In die Falle gegangen: Bislang unbekannte Nicht-Häm-FeIVO-Zwischenstufen können beim Zerfall von FeIIIOOR durch Additionsreaktionen mit Lewis-Basen abgefangen werden (siehe Bild). Grün: Lewis-Base, rot: O, violett: Fe.
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