Formselektive Hydrierungen und Oxidationen an platinhaltigen, ultramikroporösen Heteropolyoxometallaten†
Yusuke Yoshinaga
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Search for more papers by this authorKohei Seki
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Search for more papers by this authorDr. Teruyuki Nakato
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Search for more papers by this authorCorresponding Author
Prof. Toshio Okuhara
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]Search for more papers by this authorYusuke Yoshinaga
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Search for more papers by this authorKohei Seki
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Search for more papers by this authorDr. Teruyuki Nakato
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Search for more papers by this authorCorresponding Author
Prof. Toshio Okuhara
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]
Graduate School of Environmental Earth Science, Hokkaido University Sapporo 060 (Japan) Telefax: Int. + 11/757-5995 E-mail: [email protected]Search for more papers by this authorDiese Arbeit wurde vom japanischen Ministerium für Erziehung, Wissenschaft, Sport und Kultur unterstützt (Grant-in-Aid for Scientific Research on Priority Areas No. 08232202).
Abstract
Bevorzugt die kleineren Moleküle werden in Gegenwart der ultramikroporösen (Porendurchmesser <5.9 Å), platinhaltigen (0.5 Gew.-%) Heteropolyoxometallatverbindung Pt/Cs2.1H0.9PW12O40 oxidiert und hydriert. Dies ergaben Untersuchungen mit Methan/2,2-Dimethylpropan bzw. Ethen/Cyclohexen (schematische Darstellung rechts).
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