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Spontane Bildung stabiler Phosphino(silyl)carbene aus instabilen Diazoverbindungen

Dr. Gregory R. Gillette

Laboratoire de Chimie de Coordination du CNRS, UP 8241, lié par conventions à l'Université Paul Sabatier et à l'Institut National Polytechnique, 205 route de Narbonne, F-31077 Toulouse Cédex (Frankreich)

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Dr. Antoine Baceiredo,

Dr. Antoine Baceiredo

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Dr. Guy Bertrand,

Corresponding Author

Dr. Guy Bertrand

Dr. Gregory R. Gillette,

Dr. Gregory R. Gillette

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Dr. Antoine Baceiredo,

Dr. Antoine Baceiredo

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Dr. Guy Bertrand,

Corresponding Author

Dr. Guy Bertrand

First published: Dezember 1990

https://doi.org/10.1002/ange.19901021233

Citations: 25

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Abstract

Mehrere Wochen in Lösung stabil sind die carbenähnlichen Verbindungen 1, die aus Phosphanyldiazomethanen bereits bei T ≤ 35°C nahezu quantitativ entstehen, wenn der Tetramethylpiperidin(tmp)-Rest einer der Substituenten am Phosphor ist. Die Verbindungen 1 reagieren mit Ausnahme von 1a mit tBuNC zu den Keteniminen 2. a, R = NiPr₂, R′ = Me; b, R = NMe₂, R′ = Me; c, R = NMe₂, R′ = iPr; d, R = Ph, R′ = Me.

References

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Volume102, Issue12

Dezember 1990

Pages 1486-1488

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Spontane Bildung stabiler Phosphino(silyl)carbene aus instabilen Diazoverbindungen

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Spontane Bildung stabiler Phosphino(silyl)carbene aus instabilen Diazoverbindungen

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