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Arene–Perfluoroarene Interactions as Physical Cross-Links for Hydrogel Formation

Andreas F. M. Kilbinger Dr.

California Institute of Technology Division of Chemistry and Chemical Engineering Mail code 164-30, Pasadena, CA 91125, USA, Fax: (+1) 626-5649297

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Robert H. Grubbs Prof. Dr.,

Robert H. Grubbs Prof. Dr.

[email protected]

California Institute of Technology Division of Chemistry and Chemical Engineering Mail code 164-30, Pasadena, CA 91125, USA, Fax: (+1) 626-5649297

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Andreas F. M. Kilbinger Dr.,

Andreas F. M. Kilbinger Dr.

California Institute of Technology Division of Chemistry and Chemical Engineering Mail code 164-30, Pasadena, CA 91125, USA, Fax: (+1) 626-5649297

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Robert H. Grubbs Prof. Dr.,

Robert H. Grubbs Prof. Dr.

[email protected]

California Institute of Technology Division of Chemistry and Chemical Engineering Mail code 164-30, Pasadena, CA 91125, USA, Fax: (+1) 626-5649297

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First published: 02 May 2002

https://doi.org/10.1002/1521-3773(20020503)41:9<1563::AID-ANIE1563>3.0.CO;2-7

Citations: 89

We thank the Office of Naval Research for funding this work. AFMK thanks the Humboldt-Foundation for a Feodor-Lynen Fellowship. We thank Rob Lammertink for help with the rheology measurements.

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Graphical Abstract

Stiff PEGs: Aqueous solutions of pyrene end-capped poly(ethylene glycol)s (PEGs) increase their viscosity in the presence of octafluoronaphthalene possibly as a result of aggregation by face-to-face stacking (shown schematically). The exploitation of the arene–perfluoroarene supramolecular synthon in solution is reported.

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Volume41, Issue9

May 3, 2002

Pages 1563-1566

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In Celebration of Robert H. Grubbs

Arene–Perfluoroarene Interactions as Physical Cross-Links for Hydrogel Formation

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