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Polymerization of Ureidopyrimidinone-Functionalized Olefins by Using Late-Transition Metal Ziegler–Natta Catalysts: Synthesis of Thermoplastic Elastomeric Polyolefins

Lee R. Rieth

Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University Ithaca, NY 14853-1301 Fax: (+1) 607-255-4137

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Robert F. Eaton,

Robert F. Eaton

Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University Ithaca, NY 14853-1301 Fax: (+1) 607-255-4137

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Geoffrey W. Coates Prof.,

Geoffrey W. Coates Prof.

[email protected]

Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University Ithaca, NY 14853-1301 Fax: (+1) 607-255-4137

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Lee R. Rieth,

Lee R. Rieth

Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University Ithaca, NY 14853-1301 Fax: (+1) 607-255-4137

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Robert F. Eaton,

Robert F. Eaton

Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University Ithaca, NY 14853-1301 Fax: (+1) 607-255-4137

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Geoffrey W. Coates Prof.,

Geoffrey W. Coates Prof.

[email protected]

Department of Chemistry and Chemical Biology, Baker Laboratory Cornell University Ithaca, NY 14853-1301 Fax: (+1) 607-255-4137

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First published: 28 May 2001

https://doi.org/10.1002/1521-3757(20010601)113:11<2211::AID-ANGE2211>3.0.CO;2-L

Citations: 28

This work was supported by the Eastman Chemical Company and the Cornell Nanobiotechnology Center (which is supported in part by the STC Program of the National Science Foundation (NSF); ECS-9876771). This work made use of the Cornell Center for Materials Research Shared Experimental Facilities, supported through the NSF Materials Research Science and Engineering Centers program (DMR-0079992). G.W.C. gratefully acknowledges a David and Lucile Packard Foundation Fellowship in Science and Engineering, an Alfred P. Sloan Research Fellowship, an NSF CAREER Award (CHE-9875261), an Arnold and Mabel Beckman Foundation Young Investigator Award, a Camille Dreyfus Teacher-Scholar Award, a 3M Untenured Faculty Grant, and a Union Carbide Innovation Recognition Award. We thank Prof. E. W. Meijer and Dr. S. R. Turner and Dr. P. B. Mackenzie for helpful discussions.

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Graphical Abstract

Die Natur als Vorbild: Die Bildung spezifischer Wasserstoffbrücken, eine wesentliche Grundlage für Prozesse in lebenden Organismen, lässt sich im Grenzgebiet von supramolekularer Chemie und homogener Katalyse gezielt einsetzen, so bei der Synthese neuartiger Elastomere (siehe schematische Darstellung), deren Eigenschaften auf starken intermolekularen Wasserstoffbrücken beruhen.

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Volume113, Issue11

June 1, 2001

Pages 2211-2214

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Polymerization of Ureidopyrimidinone-Functionalized Olefins by Using Late-Transition Metal Ziegler–Natta Catalysts: Synthesis of Thermoplastic Elastomeric Polyolefins

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Polymerization of Ureidopyrimidinone-Functionalized Olefins by Using Late-Transition Metal Ziegler–Natta Catalysts: Synthesis of Thermoplastic Elastomeric Polyolefins

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