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Dehydrogenative Dimerization of Tin Hydrides Catalyzed by Ruthenium–Allenylidene Complexes

Susan M. Maddock Dr.

Department of Chemistry The Scripps Research Institute 10550 North Torrey Pines Rd., La Jolla, CA 92037 (USA) Fax: (+1) 858-784-8850

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M. G. Finn Prof.,

M. G. Finn Prof.

[email protected]

Department of Chemistry The Scripps Research Institute 10550 North Torrey Pines Rd., La Jolla, CA 92037 (USA) Fax: (+1) 858-784-8850

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Susan M. Maddock Dr.,

Susan M. Maddock Dr.

Department of Chemistry The Scripps Research Institute 10550 North Torrey Pines Rd., La Jolla, CA 92037 (USA) Fax: (+1) 858-784-8850

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M. G. Finn Prof.,

M. G. Finn Prof.

[email protected]

Department of Chemistry The Scripps Research Institute 10550 North Torrey Pines Rd., La Jolla, CA 92037 (USA) Fax: (+1) 858-784-8850

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First published: 28 May 2001

https://doi.org/10.1002/1521-3757(20010601)113:11<2196::AID-ANGE2196>3.0.CO;2-I

Citations: 13

We thank The Skaggs Institute for Chemical Biology at The Scripps Research Institute for support of this work; S.M.M. is a Skaggs Postdoctoral Fellow. We are also grateful to Dr. Michal Sabat (University of Virginia) for X-ray crystallography and Prof. David Goodin (The Scripps Research Institute) for the EPR experiment described in ref. 14.

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Graphical Abstract

Konjugation erforderlich: Die Umsetzung von Zinnhydriden zu Distannanen und Diwasserstoff lässt sich durch Allenylidenruthenium-Komplexe katalysieren (siehe Schema). Alkinyl- oder Alkenylgruppen als Reste R, die in Konjugation mit dem Arenring stehen, sind für die katalytische Aktivität notwendig – ein ungewöhnliches Beispiel für die Kontrolle der Reaktivität eines Metallzentrums durch einen entfernten Substituenten.

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References

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Volume113, Issue11

June 1, 2001

Pages 2196-2199

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Dehydrogenative Dimerization of Tin Hydrides Catalyzed by Ruthenium–Allenylidene Complexes

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Dehydrogenative Dimerization of Tin Hydrides Catalyzed by Ruthenium–Allenylidene Complexes

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