Remote Stereocontrol in Carbonyl Additions Promoted by Vinylstannanes
Asunción Barbero Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorFrancisco J. Pulido Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorJuan A. Rincón Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorPurificación Cuadrado Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorDiego Galisteo Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorHenar Martínez-García Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorAsunción Barbero Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorFrancisco J. Pulido Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorJuan A. Rincón Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorPurificación Cuadrado Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorDiego Galisteo Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorHenar Martínez-García Dr.
Departamento de Química Orgánica, Universidad de Valladolid 47011 Valladolid (Spain) Fax: (+34) 983-423013
Search for more papers by this authorWe Thank the M.E.C. of Spain (PB96/0357) and the Junta de Castilla y León (VA43/98) for financial support. We are very much indebted to Dr. Santiago García-Granda, Oviedo (Spain) for X-ray crystallographic assistance.
Graphical Abstract
Syn zum Zinn – dies ist die bevorzugte Orientierung bei der Addition von Organolithiumreagentien an die Carbonylgruppe cyclischer Ketone mit einer β-Stannylvinylgruppe. Diese stereochemische Fernkontrolle resultiert daraus, dass das Organolithiumreagens wie im Bild gezeigt zwischen Zinnatom und Carbonylgruppe verankert wird.
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