Constructing Artificial Zincophilic Interphases Based on Indium–Organic Frameworks as Zinc Dendrite Constraint for Rechargeable Zinc–Air Battery
Ling Liu
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
Search for more papers by this authorSaifei Ma
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
Search for more papers by this authorCorresponding Author
Ya-Ping Deng
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorBing Tang
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029 P. R. China
Search for more papers by this authorYining Zhang
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
Search for more papers by this authorWensheng Yan
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029 P. R. China
Search for more papers by this authorCorresponding Author
Yi Jiang
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Zhongwei Chen
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorLing Liu
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
Search for more papers by this authorSaifei Ma
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
Search for more papers by this authorCorresponding Author
Ya-Ping Deng
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorBing Tang
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029 P. R. China
Search for more papers by this authorYining Zhang
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
Search for more papers by this authorWensheng Yan
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, 230029 P. R. China
Search for more papers by this authorCorresponding Author
Yi Jiang
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Zhongwei Chen
Power Battery and Systems Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
The practical application of zinc (Zn)–air batteries is largely restricted by their inferior cyclability, especially under fast-charging conditions. Uneven Zn plating and dendrite formation result in their short circuits. In this work, an artificial solid-electrolyte interphase (SEI) is constructed using indium–organic frameworks (IOF) on the Zn anode. It contains a hybrid architecture that integrates chemical and morphological contributions to regulate Zn plating behaviors and constrain dendrite growth. The atomically dispersed In3+ provides zincophilic sites to tune Zn nucleation kinetics and promote preferential growth along (002) crystal facet. Meanwhile, IOF exhibits nanosheets-assembled microspheres with a well-ordered porous architecture, which promotes mass transfer and affords space for Zn electrodeposition. The influence of SEI microstructure on Zn plating/stripping behavior is further investigated and validated by the post-cycling characterizations. With IOF based SEI, Zn symmetric cells perform stable cycling for over 1750 h at 10 mA cm−2. When powering Zn–air batteries, their cycling life is extended to 800 h, which is approximately four times longer than that of pristine Zn foil.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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