The Janus-SAM Approach for the Flexible Functionalization of Gold and Titanium Oxide Surfaces
Rahila Bhat
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorStephan Sell
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorRalf Wagner
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorJian Tao Zhang
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorChangjiang Pan
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorBora Garipcan
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorWilhelm Boland
Director of Bioorganic Chemistry Department of Bioorganic Chemistry Max Planck Institute for Chemical Ecology Hans-Knöll-Straße, 07745 Jena (Germany)
Search for more papers by this authorJörg Bossert
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorElisabeth Klemm
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorCorresponding Author
Klaus D. Jandt
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany).Search for more papers by this authorRahila Bhat
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorStephan Sell
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorRalf Wagner
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorJian Tao Zhang
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorChangjiang Pan
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorBora Garipcan
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorWilhelm Boland
Director of Bioorganic Chemistry Department of Bioorganic Chemistry Max Planck Institute for Chemical Ecology Hans-Knöll-Straße, 07745 Jena (Germany)
Search for more papers by this authorJörg Bossert
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorElisabeth Klemm
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Search for more papers by this authorCorresponding Author
Klaus D. Jandt
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany)
Director & Chair in Materials Science Institute of Materials Science & Technology (IMT) Friedrich-Schiller-University (FSU) Löbdergraben 32, 07743 Jena (Germany).Search for more papers by this authorAbstract
A novel approach is developed to address the requirement of multiple stamps and inks for microcontact printing (µCP) onto different substrate surfaces. This approach relies on µCP one divalent molecule, which is able to form Janus self-assembled monolayers (JSAMs) with a labile cleavable centre, thus providing a facile method for the chemical derivatization of different substrate surfaces. This study presents an answer to the challenges presented within a highly versatile application, µCP. N-(3-diethylphosphatoxy)propyl-11-mercaptoundecanamide is used for the first time as an ink for µCP onto both gold and titanium oxide surfaces, utilizing the same polydimethylsiloxane stamp. Following printing, the JSAMs are enzymatically treated on these two different substrates to reveal different functional groups. The newly formed surfaces are subjected to additional surface reactions and used for the chemisorption of bovine serum albumin. At each stage, these JSAMs are characterized by X-ray photoelectron spectroscopy and dynamic water-contact-angle measurements. Confocal laser scanning microscopy is used for the characterization of the adsorbed proteins.
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