Volume 18, Issue 5 pp. 1223-1228
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Effective potential model for calculating the energy shift in the ground state of two-electron atoms

Pratibha Jolly

Pratibha Jolly

Department of Physics and Astrophysics, University of Delhi, Delhi-11007, India

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Kamalni Sane

Kamalni Sane

Department of Chemistry, Daulat Ram College, University of Delhi, Delhi-110007, India

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K. V. Sane

K. V. Sane

Department of Chemistry, University of Delhi, Delhi-110007, India

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First published: November 1980

Abstract

An effective operator for the electron–electron interaction derived earlier has been shown to be successful for calculating the ground-state energy shift values for 10 members of the helium isoelectronic sequence in terms of a single free parameter. Some possible applications of the modified interaction operator for semiempirical calculations are suggested.

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