Stretch-Induced Melting and Recrystallization of Polyethylene-Plasticizer Film Studied by In Situ X-Ray Scattering: A Thermodynamic Point of View
Xiaowei Chen
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorWenwen Zhang
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorKe Ye
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorCorresponding Author
Lingpu Meng
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Correspondence to: L. Meng: (E-mail: [email protected])Search for more papers by this authorFei Lv
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorTian Cao
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorCaixia Wan
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorXin Chen
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorLiangbin Li
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorXiaowei Chen
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorWenwen Zhang
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorKe Ye
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorCorresponding Author
Lingpu Meng
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Correspondence to: L. Meng: (E-mail: [email protected])Search for more papers by this authorFei Lv
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorTian Cao
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorCaixia Wan
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorXin Chen
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorLiangbin Li
National Synchrotron Radiation Laboratory, CAS Key Laboratory of Soft Matter Chemistry, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, University of Science and Technology of China, Hefei, 230026 China
Search for more papers by this authorABSTRACT
With in situ synchrotron radiation X-ray scattering, the structural alteration of polyethylene-plasticizer film during uniaxial stretching is studied at temperature far below melting point of crystal. By analyzing the evolution rule of structural parameters quantitatively, stretch-induced melting and recrystallization process is validated to be the underlying mechanism of plastic deformation for the system. The physical essence of stretch-induced melting is proved to be phase transition driven by elastic energy which originates from lattice deformation. Conversely, the recrystallization process is proved to be controlled by temperature; furthermore, the growth of lamellae during recrystallization is in perfect accordance with kinetic theory by Lauritzen and Hoffman. This study provides a quantitative understanding to the long-existing melting–recrystallization model from a thermodynamics point of view. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 1521–1528
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