Synthesis of highly polymerizable 1,3-benzoxazine assisted by phenyl thio ether and hydroxyl moieties
Asei W. Kawaguchi
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Search for more papers by this authorAtsushi Sudo
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Search for more papers by this authorCorresponding Author
Takeshi Endo
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, JapanSearch for more papers by this authorAsei W. Kawaguchi
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Search for more papers by this authorAtsushi Sudo
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Search for more papers by this authorCorresponding Author
Takeshi Endo
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Molecular Engineering Institute, Kinki University, Kayanomori, Iizuka, Fukuoka 820-8555, JapanSearch for more papers by this authorGraphical Abstract
A benzoxazine bearing thiol moiety 1 was synthesized from its precursor, a bifunctional benzoxazine bearing disulfide linkage, through selective reduction of the disulfide. The thiol moiety thus formed readily reacted with glycidyl phenyl ether to give the corresponding benzoxazine 3a, which exhibited much higher polymerization ability than some referential monomers without sulfide moiety.
Supporting Information
Additional Supporting Information may be found in the online version of this article.
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