Polymer–silicate nanocomposites produced by in situ atom transfer radical polymerization
Hanying Zhao
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Search for more papers by this authorS. Dayana Argoti
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Search for more papers by this authorBrendan P. Farrell
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Search for more papers by this authorCorresponding Author
Devon A. Shipp
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810Search for more papers by this authorHanying Zhao
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Search for more papers by this authorS. Dayana Argoti
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Search for more papers by this authorBrendan P. Farrell
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Search for more papers by this authorCorresponding Author
Devon A. Shipp
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810
Department of Chemistry and Center for Advanced Materials Processing, Clarkson University, Potsdam, New York 13699-5810Search for more papers by this authorAbstract
Polymer–silicate nanocomposites were synthesized with atom transfer radical polymerization (ATRP). An ATRP initiator, consisting of a quaternary ammonium salt moiety and a 2-bromo-2-methyl propionate moiety, was intercalated into the interlayer spacings of the layered silicate. Subsequent ATRP of styrene, methyl methacrylate, or n-butyl acrylate with Cu(I)X/N,N-bis(2-pyridiylmethyl) octadecylamine, Cu(I)X/N,N,N′,N′,N″-pentamethyldiethylenetriamine, or Cu(I)X/1,1,4,7,10,10-hexamethyltriethylenetetramine (X = Br or Cl) catalysts with the initiator-modified silicate afforded homopolymers with predictable molecular weights and low polydispersities, both characteristics of living radical polymerization. The polystyrene nanocomposites contained both intercalated and exfoliated silicate structures, whereas the poly(methyl methacrylate) nanocomposites were significantly exfoliated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 916–924, 2004
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